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UN1873 高氯酸,按质量计,含酸大于50%但不大于72%

PERCHLORIC ACID with more than 50% but not more than 72% acid, by mass

IMDG Code 42-24 第5.1类 包装类别 I 更新 2026-09-08

基本信息

UN 编号UN1873
中文名称高氯酸,按质量计,含酸大于50%但不大于72%
英文名称PERCHLORIC ACID with more than 50% but not more than 72% acid, by mass
危险类别第5.1类(副危险 8)
包装类别I
海洋污染物
有限数量0
例外数量E0
EmS 应急措施F-A,S-Q(F-A, S-Q)

物质性质与外观

无色液体。与可燃物混合会自 燃。遇火时,撞击或摩擦,能 引起爆炸。对大多数金属有强 腐蚀性。灼伤皮肤、眼睛和粘 膜。禁止大量运输酸含量大于 72%的高氯酸。

Colourless liquid. Mixtures with combustible material may ignite spontaneously and, when involved in a fire, by shock or by friction, may cause an explosion. Highly corrosive to most metals. Causes burns to skin, eyes and mucous membranes. Transport of PERCHLORIC ACID with more than 72% acid, by mass, is prohibited.

出处:IMDG Code 42-24 第 659 页

包装要求

本条目适用的包装导则: P502 ;有限数量 0,例外数量 E0。

P502

P502 只要符合第4.1.1和4.1.3节的一般规定,允许使用下列包装: 组合包装最大净重玻璃 5 L 桶金属 5 L 钢(1A1、1A2) 125kg 塑料 5 L 铝(1B1、1B2) 125kg 其他金属(1N1、1N2) 125kg 胶合板(1D) 125kg 纤维质(1G) 125kg 塑料(1H1、1H2) 125kg 箱钢(4A) 125kg 铝(4B) 125kg 其它金属(4N) 125kg 天然木(4C1) 125kg 天然木,箱壁防筛漏(4C2) 125kg 胶合板(4D) 125kg 再生木(4F) 125kg 纤维板(4G) 125kg 可发性塑料(4H1) 60kg 硬塑料(4H2) 125kg 单一包装最大容积桶钢(1A1) 250L 铝(1B1) 250L 塑料(1H1) 250L 罐钢(3A1) 60L 铝(3B1) 60L 塑料(3H1) 60L 复合包装装于钢或铝桶内的塑料容器(6HA1、6HB1) 250L P502 装于纤维、塑料或胶合板桶内的塑料容器(6HG1、6HH1、 250L 6HD1) 装于钢或铝板条箱或箱内的塑料容器或装于木质、胶合板、纤 60L 维板或硬塑料箱内的塑料容器(6HA2、6HB2、6HC、6HD2、 6HG2或6HH2) 装于钢、铝、纤维或胶合板桶内的玻璃容器(6PA1、6PB1、 60L 6PD1或6PG1),或装于钢、铝、木质或纤维板箱内或藤条筐内的玻璃容器(6PA2、6PB2、6PC、6PD2或6PG2)或装于硬质或泡沫塑料容器内的玻璃容器(6PH1或6PH2)。 特殊包装规定: PP28 对于UN 1873,包装直接与高氯酸接触的部件须由玻璃或塑料制成。

P502 The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met. Combination packagings Maximum net mass Glass 5 L Drums Metal 5 L steel (1A1, 1A2) 125 kg Plastic 5 L aluminium (1B1, 1B2) 125 kg other metal (1N1, 1N2) 125 kg plywood (1D) 125 kg fibre (1G) 125 kg plastics (1H1, 1H2) kg Boxes steel (4A) 125 kg aluminium (4B) 125 kg other metal (4N) 125 kg natural wood (4C1) 125 kg natural wood with sift-proof 125 kg walls (4C2) plywood (4D) 125 kg reconstituted wood (4F) 125 kg fibreboard (4G) 125 kg expanded plastics (4H1) 60 kg solid plastics (4H2) 125 kg Single packagings Maximum capacity Drums steel (1A1) 250 L aluminium (1B1) 250 L plastics (1H1) 250 L Jerricans steel (3A1) 60 L aluminium (3B1) 60 L plastics (3H1) 60 L Composite packagings Plastics receptacle in steel or aluminium drum (6HA1, 6HB1) 250 L Plastics receptacle in fibre, plastics or plywood drum (6HG1, 6HH1, 6HD1) 250 L Plastics receptacle in steel or aluminium crate or box or plastics receptacle in 60 L wood, plywood, fibreboard or solid plastics box (6HA2, 6HB2, 6HC, 6HD2, 6HG2 or 6HH2) Glass receptacle in steel, aluminium, fibre or plywood drum (6PA1, 6PB1, 6PD1 or 60 L 6PG1) or in a steel, aluminium, wood or fibreboard box or in wickerwork hamper (6PA2, 6PB2, 6PC, 6PG2 or 6PD2) or in expanded or solid plastics packaging (6PH1 or 6PH2) Special packing provision: PP28 For UN No. 1873, parts of packagings which are in direct contact with perchloric acid shall be constructed of glass or plastics.

出处:IMDG Code 42-24 第 213 页(4.1.4.1)

包装特殊规定

PP28

对于UN 1873,包装直接与高氯酸接触的部件须由玻璃或塑料制成。

For UN No. 1873, parts of packagings which are in direct contact with perchloric acid shall be constructed of glass or plastics.

中型散装容器(IBC)要求

本条目无中型散装容器(IBC)运输要求。

罐柜运输要求

T10

T1-T22 本可移动罐柜导则适用于第1类和第3至9类液体和固体物质,须满足第4.2.1节的一般规定和第6.7.2节的要求。带 FRP 外壳的可移动罐柜导则适用于第 1、3、5.1、6.1、6.2、8 和 9 类或小类物质。此外,第 6.10 章的规定适用于带 FRP 外壳的可移动罐柜。 最小罐壳厚度底部开口最低试验 (单位: mm-标准安全减压规定a 规定b 可移动罐柜导则压力钢) (见第6.7.2.8 (见第6.7.2.6 (bar) (见第6.7.2.4 条) 条) 条) 4 6mm 见6.7.2.8.3 不允许

S T1 – T22 These portable tank instructions apply to liquid and solid substances of class 1 and classes 3 to 9. The general provisions of section 4.2.1 and the requirements of section 6.7.2 shall be met. The instructions for portable tanks with FRP shells apply to substances of classes or divisions 1, 3, 5.1, 6.1, 6.2, 8 and 9. Additionally, the provisions of chapter 6.10 apply to the portable tanks with FRP shells. Minimum shell thickness Pressure relief Bottom opening (in mm – reference provisionsa provisionsb instruction pressure (bar) steel) (see 6.7.2.8) (see 6.7.2.6) (see 6.7.2.4) 4 6 mm See 6.7.2.8.3 Not allowed

罐柜特殊规定

TP1

不得超过第4.2.1.9.条中规定的充灌度。

The degree of filling prescribed in 4.2.1.9.2 shall not be exceeded.

运输标签与标记

本货物包件应张贴以下标签与标记:

氧化剂 5.1 5.1
氧化剂 5.1
腐蚀性物质 8 8
腐蚀性物质 8

特殊规定(Special Provisions)

本条目适用特殊规定: 900

SP 900

禁止运输下列物质: 次氯酸铵硝酸铵,易于自热并足以引发其分解亚硝酸铵和无机亚硝酸铵盐的混合物,含有浓度超过10%的氯酸水溶液亚硝酸乙酯,纯的氢氰酸水溶液(氰化氢水溶液) 含20% 以上氰化氢氯化氢,冷冻液氰化氢溶液,在醇中,含氰化氢超过45% 亚硝酸甲酯高氯酸,按质量含酸超过72% 苦味酸银,干的或湿的,按质量含水少于30%亚硝酸锌铵另见特殊规定349、350、351、352和353。

The transport of the following substances is prohibited: AMMONIUM HYPOCHLORITE AMMONIUM NITRATE liable to self-heating sufficient to initiate decomposition AMMONIUM NITRITES and mixtures of an inorganic nitrite with an ammonium salt CHLORIC ACID, AQUEOUS SOLUTION with more than 10% chloric acid ETHYL NITRITE pure HYDROCYANIC ACID, AQUEOUS SOLUTION (HYDROGEN CYANIDE, AQUEOUS SOLUTION) with more than 20% hydrogen cyanide HYDROGEN CHLORIDE, REFRIGERATED LIQUID HYDROGEN CYANIDE SOLUTION, IN ALCOHOL with more than 45% hydrogen cyanide MERCURY OXYCYANIDE pure METHYL NITRITE PERCHLORIC ACID with more than 72% acid, by mass SILVER PICRATE, dry or wetted with less than 30% water by mass ZINC AMMONIUM NITRITE See also special provisions 349, 350, 351, 352 and 353.

出处:IMDG Code 42-24 第 792 页

积载与隔离

积载与操作积载类D(Category D)
隔离SGG1 SG16 SG36 SG49

隔离组(7.2.5.2)

SGG1

1 酸类

1 acids

隔离代码(7.2.8)

SG16

与第4.1类“隔离”。

Stow “separated from” class 4.1.

SG36

与SGG18 - 碱类“隔离”。

Stow “separated from” SGG18 – alkalis.

SG49

与SGG8 - 氰化物“隔离”。

Stow “separated from” SGG6 – cyanides.

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