UN1994 五羰基铁

黄色到深红色，挥发性易燃液 体。闪点：-15℃c.c。爆炸极 限：3.7%至12.5%。与水或水 蒸气会反应，放出一氧化碳毒 性气体。吞咽、与皮肤接触或 吸入会严重中毒。

Yellow to dark red, volatile flammable liquid. Flashpoint: 15 C c.c. - ° Explosive limits: 3.7% to 12.5%. May react with water or steam, evolving carbon monoxide, which is a toxic gas. Highly toxic if swallowed, by skin contact or by inhalation.

出处：IMDG Code 42-24 第 664 页

P601

P601 只要符合第4.1.1和4.1.3节的一般规定，且容器密封，允许使用下列包装： （1） 最大毛重为15kg的组合包装，由以下容器组成： （a）一个或多个玻璃内容器，每个内容器的最大净容量为 1L，装载量不超过其容量的 90%；其封盖须以任何能够防止运输过程中因撞击或振动而脱落或松动的方式固定，单独放置在 （b）金属容器中，连同足以吸收玻璃内容器全部内容物的衬垫材料和吸附材料，再装入 （c）1A1、1A2、1B1、1B2、1N1、1N2、1H1、1H2、1D、1G、4A、4B、4N、 4C1、4C2、4D、4F、4G或4H2外包装中。 （2） 组合包装由容量不超5L的金属或塑料内容器组成，单独包装有足以吸收内容物的吸收材料和惰性衬垫材料，装入 1A1、1A2、1B1、1B2、1N1、1N2、1H1、1H2、1D、 1G、4A、4B、4N、4C1、4C2、4D、4F、4G 或 4H2 外包装中，最大总重量为 75kg。上述内容器不得超过其容量的 90%。每个内容器的封口须用任何能够防止封口在运输过程中因撞击或振动而脱落或松动的方法固定到位。 （3） 包装组成： P601 外包装：钢桶或塑料桶（1A1、1A2、1H1、1H2），按第 6.1.5节关于单一包装规定的桶和复合包装（1A1、1B1、1N1、1H1或6HA1），但须符合下列条件：.1 液压实验须在至少3bar（表压）的压力下进行；.2 设计和生产密封性试验须在0.3bar的试验压力下进行；.3 须使用惰性减震衬垫材料将其与外桶隔离，该衬垫材料须从四周包围内包装；.4 其容量不得超过125L；.5 封盖须为螺旋盖类型，且： （i） 用任何能够防止运输过程中撞击或振动导致封盖脱落或松动的方法将其固定到位；以及 （ii） 配备封盖密封。.6 外包装和内包装须按.2定期进行密封性试验，试验间隔不得超过两年半；和.7 内包装和外包装须以清晰易读和耐久的字符标明： （i） 初次检验和最近一次定期检验的日期（月、年）； （ii） 进行检验或检验机构的名称或授权标志。 （4） 符合第 4.1.3.6 条一般规定的压力容器。压力容器须在不低于 1MPa（10bar，表压） 的压力下每 10 年进行一次初始检验和定期检验。压力容器不得配备任何压力释放装置。每个装有致死浓度LC 小于或等于200ml/m3（ppm）的吸入性有毒液体的压力容器均须使用符合以下要求塞子或阀门封闭： （a） 每个塞子或阀门均须通过锥形螺纹直接与压力容器连接，并能承受压力容器的试验压力而不损坏或泄露； （b） 每个阀门均须为无填料型，并带有无穿孔隔膜，但对于对腐蚀性材料，阀门可以是填料型，其组件通过密封盖和垫圈接头与阀体或压力容器连接，使之不透气， 以防止内装物通过或穿过填料流失； （c） 每个阀门出口均须使用螺纹盖或螺纹实心塞和惰性垫圈材料密封； （d） 压力容器、阀门、塞子、出口盖、密封剂和垫圈的制造材料须相互兼容并与所装货物相容。 任何壁厚小于 2mm 的压力容器和未安装阀门保护装置的压力容器均须使用外包装运输。压力容器不得进行歧管连接或互连。

P601 The following packagings are authorized provided the general provisions of 4.1.1 and 4.1.3 are met and the packagings are hermetically sealed: (1) Combination packagings with a maximum gross mass of 15 kg, consisting of: (a) o ne or more glass inner packaging(s) with a maximum net quantity of 1 L each and filled to not more than 90% of their capacity; the closure(s) of which shall be physically held in place by any means capable of preventing back-off or loosening by impact or vibration during transport, individually placed in (b) m etal receptacles together with cushioning and absorbent material sufficient to absorb the entire contents of the glass inner packaging(s), further packed in (c) 1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G, 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G or 4H2 outer packagings. (2) Combination packagings consisting of metal or plastics inner packagings not exceeding 5 L in capacity individually packed with absorbent material sufficient to absorb the contents and inert cushioning material in 1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1H1, 1H2, 1D, 1G, 4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G or 4H2 outer packagings with a maximum gross mass of 75 kg. Inner packagings shall not be filled to more than 90% of their capacity. The closure of each inner packaging shall be physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transport. (3) Packagings consisting of: Outer packagings: Steel or plastics drums, (1A1, 1A2, 1H1 or 1H2), tested in accordance with the test provisions in 6.1.5 at a mass corresponding to the mass of the assembled package either as a packaging intended to contain inner packagings, or as a single packaging intended to contain solids or liquids, and marked accordingly. Inner packagings: Drums and composite packagings (1A1, 1B1, 1N1, 1H1 or 6HA1), meeting the provisions of chapter 6.1 for single packagings, subject to the following conditions:.1 the hydraulic pressure test shall be conducted at a pressure of at least 3 bar (gauge pressure);.2 the design and production leakproofness tests shall be conducted at a test pressure of 0.30 bar;.3 they shall be isolated from the outer drum by the use of inert shock-mitigating cushioning material which surrounds the inner packaging on all sides;.4 their capacity shall not exceed 125 L;.5 closures shall be of a screw-cap type that are: (i) physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transport; and (ii) provided with a cap seal..6 The outer and inner packagings shall be subjected periodically to a leakproofness test according to.2 at intervals of not more than two and a half years; and 4.7 The outer and inner packagings shall bear in clearly legible and durable characters: (i) the date (month, year) of the initial testing and the latest periodic test; (ii) the name or authorized symbol of the party performing the tests and inspections. (4) Pressure receptacles, provided that the general provisions of 4.1.3.6 are met. They shall be subjected to an initial test and periodic tests every 10 years at a pressure of not less than 1 MPa (10 bar) (gauge pressure). Pressure receptacles may not be equipped with any pressure relief device. Each pressure receptacle containing a toxic by inhalation liquid with an LC less than or equal to 200 mL m3 (ppm) shall be closed with a plug or valve / conforming to the following: (a) Each plug or valve shall have a taper-threaded connection directly to the pressure receptacle and be capable of withstanding the test pressure of the pressure receptacle without damage or leakage; (b) Each valve shall be of the packless type with non-perforated diaphragm, except that, for corrosive materials, a valve may be of the packed type with an assembly made gas-tight by means of a seal cap with gasket joint attached to the valve body or the pressure receptacle to prevent loss of material through or past the packing; (c) Each valve outlet shall be sealed by a threaded cap or threaded solid plug and inert gasket material; (d) The materials of construction for the pressure receptacle, valves, plugs, outlet caps, luting and gaskets shall be compatible with each other and with the lading. Each pressure receptacle with a wall thickness at any point of less than 2.0 mm and each pressure receptacle that does not have fitted valve protection shall be transported in an outer packaging. Pressure receptacles shall not be manifolded or interconnected.

出处：IMDG Code 42-24 第 218 页（4.1.4.1）

T22

T1-T22 本可移动罐柜导则适用于第1类和第3至9类液体和固体物质，须满足第4.2.1节的一般规定和第6.7.2节的要求。带 FRP 外壳的可移动罐柜导则适用于第 1、3、5.1、6.1、6.2、8 和 9 类或小类物质。此外，第 6.10 章的规定适用于带 FRP 外壳的可移动罐柜。 最小罐壳厚度底部开口最低试验 （单位: mm-标准安全减压规定a 规定b 可移动罐柜导则压力钢） （见第6.7.2.8 （见第6.7.2.6 （bar） （见第6.7.2.4 条） 条） 条） 10 10mm 见6.7.2.8.3 不允许 a 当标明“正常”时，除第6.7.2.8.3条外，第6.7.2.8条的所有规定均适用。 b 当此栏标明“不允许”时，当运输的物质为液体时，不允许底部开口（见第6.7.2.6.1条）。 当运输的物质在正常运输条件下遇到的所有温度下均为固体时，允许符合第6.7.2.6.2条规定的底部开口。

S T1 – T22 These portable tank instructions apply to liquid and solid substances of class 1 and classes 3 to 9. The general provisions of section 4.2.1 and the requirements of section 6.7.2 shall be met. The instructions for portable tanks with FRP shells apply to substances of classes or divisions 1, 3, 5.1, 6.1, 6.2, 8 and 9. Additionally, the provisions of chapter 6.10 apply to the portable tanks with FRP shells. Minimum shell thickness Pressure relief Bottom opening (in mm – reference provisionsa provisionsb instruction pressure (bar) steel) (see 6.7.2.8) (see 6.7.2.6) (see 6.7.2.4) 10 10 mm See 6.7.2.8.3 Not allowed a When the word “Normal” is indicated, all the provisions of 6.7.2.8 apply except for 6.7.2.8.3. b When this column indicates “not allowed”, bottom openings are not permitted when the substance to be transported is a liquid (see 6.7.2.6.1). When the substance to be transported is a solid at all temperatures encountered under normal conditions of transport, bottom openings conforming to the provisions of 6.7.2.6.2 are authorized.

不得超过第4.2.1.9.3条中规定的充灌度。

The degree of filling prescribed in 4.2.1.9.3 shall not be exceeded.

运输该物质时须配备自给式呼吸器，除非船上未配备《安全公约》第 II- 2/19（II-2/54）条所要求的的自给式呼吸器。

Self-contained breathing apparatus shall be provided when this substance is transported, unless no self-contained breathing apparatus, as required by SOLAS regulation II-2/19 (II-2/54), is on board.

SP 354

此物质吸入有毒。

This substance is toxic by inhalation.

出处：IMDG Code 42-24 第 779 页

避开生活居住处所。

Clear of living quarters.