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UN3243 含有毒液体的固体,未另列明的

SOLIDS CONTAINING TOXIC LIQUID, N.O.S.

IMDG Code 42-24 第6.1类 包装类别 II 更新 2026-09-08

基本信息

UN 编号UN3243
中文名称含有毒液体的固体,未另列明的
英文名称SOLIDS CONTAINING TOXIC LIQUID, N.O.S.
危险类别第6.1类
包装类别II
海洋污染物
有限数量500 g
例外数量E4
EmS 应急措施F-A,S-A(F-A, S-A)

物质性质与外观

非危险性固体物质(如泥土、沙 子、生产材料等)与有毒液体的 混合物。吞咽、与皮肤接触或 吸入会中毒。

Mixtures of non-dangerous solids (such as soil, sand, production materials, etc.) and toxic liquids. Toxic if swallowed, by skin contact or by inhalation.

出处:IMDG Code 42-24 第 735 页

包装要求

本条目适用的包装导则: P002 ;有限数量 500 g,例外数量 E4。

P002

(固体) P002 只要符合第4.1.1和4.1.3节的一般规定,允许使用下列包装: 组合包装最大净重(见第4.1.3.3条) 玻璃 10kg 桶塑料1 30kg 钢(1A1、1A2) 125kg 400kg 400kg 金属 40kg 铝(1B1、1B2) 125kg 400kg 400kg 纸1, 2, 3 50kg 其它金属 125kg 400kg 400kg 纤维1, 2, 3 50kg (1N1,1N2) 125kg 400kg 400kg 塑料(1H1,1H2) 125kg 400kg 400kg 胶合板(1D) 125kg 400kg 400kg 纤维(1G) 箱钢(4A) 125kg 400kg 400kg 铝(4B) 125kg 400kg 400kg 其它金属(4N) 125kg 400kg 400kg 天然木(4C1) 125kg 400kg 400kg 天然木, 250kg 400kg 400kg 箱壁防筛漏(4C2) 这些内包装须防胶合板(4D) 125kg 400kg 400kg 泄漏。 再生木(4F) 125kg 400kg 400kg 在运输途中物质纤维板(4G) 75kg 400kg 400kg 可能成为液体时, 可发性塑料(4H1) 40kg 60kg 60kg 不得使用这些内包硬塑料(4H2) 125kg 400kg 400kg 装。 罐纸和纤维质内包钢(3A1、3A2) 75kg 120kg 120kg 装不得用于包装类铝(3B1、3B2) 75kg 120kg 120kg I物质。 塑料(3H1、3H2) 75kg 120kg 120kg 最大净重(见第4.1.3.3条) 单一包装包装类I 包装类II 包装类III 桶钢(1A1或1A24) 400kg 400kg 400kg 铝(1B1或1B24) 400kg 400kg 400kg 金属、除了钢或铝((1N1或1N24) 400kg 400kg 400kg 塑料(1H1或1H24) 400kg 400kg 400kg 纤维质(1G5) 400kg 400kg 400kg 胶合板(1D5) 400kg 400kg 400kg (固体) P002 4这些包装不得用于装载运输途中可能变成液体的包装类I物质(见第4.1.3.4条)。 5这些包装不得用于装载运输途中可能变成液体的物质(见第4.1.3.4条)。 只要符合第4.1.1和4.1.3节的一般规定,允许使用下列包装: 罐钢(3A1或3A24) 120kg 120kg 120kg 铝(3B1或3B24) 120kg 120kg 120kg 塑料(3H1或3H24) 120kg 120kg 120kg 箱钢(4A)5 不允许 400kg 400kg 铝(4B)5 不允许 400kg 400kg 其他金属(4N)5) 不允许 400kg 400kg 天然木(4C1)5 不允许 400kg 400kg 天然木,箱壁防筛漏(4C2)5 不允许 400kg 400kg 胶合板(4D)5 不允许 400kg 400kg 再生木(4F)5 不允许 400kg 400kg 纤维板(4G)5 不允许 400kg 400kg 硬塑料(4H2)5 不允许 400kg 400kg 袋袋(5H3,5H4,5L3,5M2)5 不允许 50kg 50kg 复合包装塑料容器,置于钢、铝、胶合板、纤维质或塑 400kg 400kg 400kg 料桶内(6HA1、6HB1、6HG15、6HD15或 6HH1) 塑料容器,置于钢或铝板条箱或箱、木箱、 75kg 75kg 75kg 胶合板箱、纤维板箱或硬塑料箱内(6HA2, 6HB2,6HC,6HD25,6HG25或6HH2) 玻璃容器,置于钢、铝、胶合板或纤维质桶 75kg 75kg 75kg 内(6PA1、6PB1、6PD15或6PG15)或置于钢、铝、木、纤维板箱或在柳条篮中 (6PA2、6PB2、6PC、6PG25、或6PD25) 或置于硬的或可发性塑料包装内(6PH2或 6PH15) 4这些包装不得用于装载运输途中可能变成液体的包装类I物质(见第4.1.3.4条)。 (固体) P002 5这些包装不得用于装载运输途中可能变成液体的物质(见第 4.1.3.4条)。 压力容器,但须符合第4.1.3.6条的一般规定。 特殊包装规定: PP7 对于UN 2000,赛璐珞可以不包装地放置在托盘上运输,用塑料薄膜包裹并用钢带等适当方式紧固作为封闭货物运输组件中的单个商品运输。每个托盘不超过1000 kg。 PP8 对于UN 2002,包装的构造须确保不会因内压升高而爆炸。不得将这些物质用于气瓶和气体容器。 PP9 对于UN 3175、3243和3244,包装须符合已经通过包装类II性能标准的防漏试验的设计类型。对于UN 3175,当液体完全被密封袋中的固体材料吸收时,无需进行防漏试验。 PP11 对于UN 1309、包装类III和UN 1362,如果5H1、5L1和5M1袋用塑料袋包装并用收缩膜或拉伸膜包裹在货盘上,则允许使用5H1、5L1和5M1袋。 PP12 对于UN 2213和3077,在封闭货物运输组件中运输时,允许使用5H1、5L1和5M1 袋。 PP13 对于UN 2870下分类的物品,只允许使用符合包装类I性能指标的组合包装。 PP14 对于UN 2211、2698和3314,包装无需符合第6.1章中的性能测试要求。 PP15 对于UN 1324和2623,包装须符合包装类III性能指标。 PP20 对于UN 2217,可以使用防筛漏、防撕裂的容器。 PP30 对于UN 2471,不允许使用纸质或纤维质内包装。 PP31 对于 UN 1362、1463、1565、1575、1626、1680、1689、1698、1868、1889、 1932、2471、2545、2546、2881、3048、3088、3170、3174、3181、3182、 3189、3190、3205、3206、3341、3342、3448、3449和3450,包装须气密封口。 PP34 对于UN 2969(整颗粒豆),允许使用5H1、5L1和5M1袋。 PP37 对于UN 2590和2212,允许使用5M1袋。任何类型的袋装货物须放在封闭的货物运输组件内运输,或置于封闭的硬质外包装中运输。 PP38 对于UN 1309,只有在封闭货物运输组件或作为组件货物时,允许使用袋。 PP84 对于UN 1057,须使用符合包装类II性能标准的硬质外包装。包装的设计、构造和布置须能防止内装物移动、设备意外着火或易燃气体或液体意外泄漏。 PP85 对于UN 1748、2208、2880、3485、3486和3487,不允许使用袋。 PP92 对于UN3531和3533,包装的设计和构造须允许释放气体或蒸汽,以防止压力积聚, 因为压力积聚可能导致包装在失去稳定性时破裂。 PP100 对于 UN1309、1323、1333、1376、1435、1449、1457、1472、1476、1483、 1509、1516、1567、1869、2210、2858、2878、2968、3089、3096 和 3125,软质、纤维板或木质容器须防筛漏和防水,或须具有防筛漏和防水的内衬。

(SOLIDS) P002 The following packagings are authorized provided the general provisions of 4.1.1 and 4.1.3 are met. Combination packagings Maximum net mass (see 4.1.3.3) Glass 10 kg Drums Plastics1 30 kg steel (1A1, 1A2) 125 kg 400 kg 400 kg Metal 40 kg aluminium (1B1, 1B2) 125 kg 400 kg 400 kg Paper 1, 2, 3 50 kg other metal (1N1, 1N2) 125 kg 400 kg 400 kg Fibre1, 2, 3 50 kg plastics (1H1, 1H2) 125 kg 400 kg 400 kg plywood (1D) 125 kg 400 kg 400 kg fibre (1G) 125 kg 400 kg 400 kg Boxes steel (4A) 125 kg 400 kg 400 kg aluminium (4B) 125 kg 400 kg 400 kg other metal (4N) 125 kg 400 kg 400 kg natural wood (4C1) 125 kg 400 kg 400 kg natural wood with 250 kg 400 kg 400 kg sift-proof walls (4C2) plywood (4D) 125 kg 400 kg 400 kg These inner packagings shall reconstituted wood (4F) 125 kg 400 kg 400 kg be sift-proof. fibreboard (4G) 75 kg 400 kg 400 kg These inner packagings expanded plastics (4H1) 40 kg 60 kg 60 kg shall not be used when the substances being transported solid plastics (4H2) 125 kg 400 kg 400 kg may become liquid during Jerricans transport (see 4.1.3.4). Paper and fibre inner steel (3A1, 3A2) 75 kg 120 kg 120 kg packagings shall not be used aluminium (3B1, 3B2) 75 kg 120 kg 120 kg for substances of packing group I. plastics (3H1, 3H2) 75 kg 120 kg 120 kg Single packagings Drums steel (1A1 or 1A24) 400 kg 400 kg 400 kg aluminium (1B1 or 1B24) 400 kg 400 kg 400 kg metal, other than steel or aluminium (1N1 or 1N24) 400 kg 400 kg 400 kg plastics (1H1 or 1H24) 400 kg 400 kg 400 kg fibre (1G5) 400 kg 400 kg 400 kg plywood (1D5) 400 kg 400 kg 400 kg These packagings shall not be used for substances of packing group I that may become liquid during transport (see 4.1.3.4). These packagings shall not be used when the substances being transported may become liquid during transport (see 4.1.3.4). (SOLIDS) (continued) P002 The following packagings are authorized provided the general provisions of 4.1.1 and 4.1.3 are met. Maximum net mass (see 4.1.3.3) Single packagings (continued) Packing group I Packing group II Packing group III Jerricans steel (3A1 or 3A24) 120 kg 120 kg 120 kg aluminium (3B1 or 3B24) 120 kg 120 kg 120 kg plastics (3H1 or 3H24) 120 kg 120 kg 120 kg Boxes steel (4A)5 Not allowed 400 kg 400 kg aluminium (4B)5 Not allowed 400 kg 400 kg other metal (4N)5 Not allowed 400 kg 400 kg natural wood (4C1)5 Not allowed 400 kg 400 kg natural wood with sift-proof walls (4C2)5 Not allowed 400 kg 400 kg plywood (4D)5 Not allowed 400 kg 400 kg reconstituted wood (4F)5 Not allowed 400 kg 400 kg fibreboard (4G)5 Not allowed 400 kg 400 kg solid plastics (4H2)5 Not allowed 400 kg 400 kg Bags bags (5H3, 5H4, 5L3, 5M2)5 Not allowed 50 kg 50 kg Composite packagings Plastics receptacle in steel, aluminium, plywood, fibre or 400 kg 400 kg 400 kg plastics drum (6HA1, 6HB1, 6HG15, 6HD15, or 6HH1) Plastics receptacle in steel or aluminium crate or box, 75 kg 75 kg 75 kg wooden box, plywood box, fibreboard box or solid plastics box (6HA2, 6HB2, 6HC, 6HD25, 6HG25 or 6HH2) Glass receptacle in steel, aluminium, plywood or fibre 75 kg 75 kg 75 kg drum (6PA1, 6PB1, 6PD15 or 6PG15) or in steel, aluminium, wood, or fibreboard box or in wickerwork hamper (6PA2, 6PB2, 6PC, 6PG25 or 6PD25) or in expanded or solid plastics packaging (6PH2 or 6PH15) 4 These packagings shall not be used for substances of packing group I that may become liquid during transport (see 4.1.3.4). These packagings shall not be used when the substances being transported may become liquid during transport (see 4.1.3.4). Pressure receptacles, provided that the general provisions of 4.1.3.6 are met. Special packing provisions: PP7 For UN 2000, celluloid may be transported unpacked on pallets, wrapped in plastic film and secured by appropriate means, such as steel bands, as a single commodity in closed cargo transport units. Each pallet shall not exceed 1,000 kg. PP8 For UN 2002, packagings shall be so constructed that explosion is not possible by reason of increased internal pressure. Gas cylinders and gas receptacles shall not be used for these substances. PP9 For UN Nos. 3175, 3243 and 3244, packagings shall conform to a design type that has passed a leakproofness test at the packing group II performance level. For UN 3175 the leakproofness test is not required when the liquids are fully absorbed in solid material contained in sealed bags. PP11 For UN 1309, packing group III, and UN 1362, 5H1, 5L1 and 5M1 bags are allowed if they are overpacked in plastic bags and are wrapped in shrink or stretch wrap on pallets. PP12 For UN Nos. 2213 and 3077, 5H1, 5L1 and 5M1 bags are allowed when transported in closed cargo transport units. PP13 For articles classified under UN 2870, only combination packagings meeting the packing group I performance level are authorized. PP14 For UN Nos. 2211, 2698 and 3314, packagings are not required to meet the performance tests in chapter 6.1. PP15 For UN Nos. 1324 and 2623, packagings shall meet the packing group III performance level. PP20 For UN 2217, any sift-proof, tearproof receptacle may be used. PP30 For UN 2471, paper or fibre inner packagings are not permitted. PP31 For UN Nos. 1362, 1463, 1565, 1575, 1626, 1680, 1689, 1698, 1868, 1889, 1932, 2471, 2545, 2546, 2881, 3048, 3088, 3170, 3174, 3181, 3182, 3189, 3190, 3205, 3206, 3341, 3342, 3448, 3449 and 3450, packagings shall be hermetically sealed. PP34 For UN 2969 (as whole beans), 5H1, 5L1 and 5M1 bags are permitted. PP37 For UN Nos. 2590 and 2212, 5M1 bags are permitted. All bags of any type shall be transported in closed cargo transport units or be placed in closed rigid overpacks. PP38 For UN 1309, bags are permitted only in closed cargo transport units or as unit loads. PP84 For UN 1057, rigid outer packagings meeting the packing group II performance level shall be used. The packagings shall be designed and constructed and arranged to prevent movement, inadvertent ignition of the devices or inadvertent release of flammable gas or liquid. PP85 For UN Nos. 1748, 2208, 2880, 3485, 3486 and 3487, bags are not allowed. PP92 For UN Nos. 3531 and 3533, packagings shall be designed and constructed to permit the release of gas or vapour to prevent a build-up of pressure that could rupture the packagings in the event of loss of stabilization. PP100 For UN numbers 1309, 1323, 1333, 1376, 1435, 1449, 1457, 1472, 1476, 1483, 1509, 1516, 1567, 1869, 2210, 2858, 2878, 2968, 3089, 3096 and 3125, flexible, fibreboard or wooden packagings shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-resistant liner.

出处:IMDG Code 42-24 第 171 页(4.1.4.1)

包装特殊规定

PP9

对于UN 3175、3243和3244,包装须符合已经通过包装类II性能标准的防漏试验的设计类型。对于UN 3175,当液体完全被密封袋中的固体材料吸收时,无需进行防漏试验。

For UN Nos. 3175, 3243 and 3244, packagings shall conform to a design type that has passed a leakproofness test at the packing group II performance level. For UN 3175 the leakproofness test is not required when the liquids are fully absorbed in solid material contained in sealed bags.

中型散装容器(IBC)要求

IBC02

IBC02 只要符合第4.1.1、4.1.2和4.1.3节的一般规定,允许使用下列IBCs: 金属(31A、31B和31N); 硬质塑料(31H1和31H2); 复合包装(31HZ1)。 特殊包装规定: B5 对于盛装UN 1791、2014、2984和3149的IBCs,须配备允许在运输过程中排气的装置。排气装置的入口须设在运输过程中IBC最大充装条件下的蒸气空间内。 B8 纯物质不得使用 IBCs 运输,因为已知该物质在 50°C蒸汽压超过 110kPa,在 55°C时蒸气压超过130kPa。 B15 对于硝酸含量超过 55%的UN 2031,硬质塑料 IBCs和复合IBCs的硬质塑料内容器的允许使用期限为生产日期起两年。 B16 对于UN3375,未经主管当局批准,不得使用31A和31N型的IBCs。 B20 对于包装类II的UN 1716、1717、1736、1737、1738、1742、1743、1755、1764、 1768、1776、1778、1782、1789、1790、1796、1826、1830、1832、2031、 2308、2353、2513、2584、2796和2817,IBCs须安装两个关闭装置。

IBC02 The following IBCs are authorized, provided the general provisions of 4.1.1, 4.1.2 and 4.1.3 are met: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Special packing provisions: B5 For UN Nos. 1791, 2014, 2984 and 3149, IBCs shall be provided with a device to allow venting during transport. The inlet to the venting device shall be sited in the vapour space of the IBC under maximum filling conditions during transport. B8 The pure form of this substance shall not be transported in IBCs since it is known to have a vapour pressure of more than 110 kPa at 50C or 130 kPa at 55C. ° ° B15 For UN 2031 with more than 55% nitric acid, the permitted use of rigid plastics IBCs and of rigid plastics inner receptacles of composite IBCs shall be two years from their date of manufacture. B16 For UN 3375, IBCs of type 31A and 31N are not allowed without competent authority approval. B20 For UN Nos. 1716, 1717, 1736, 1737, 1738, 1742, 1743, 1755, 1764, 1768, 1776, 1778, 1782, 1789, 1790, 1796, 1826, 1830, 1832, 2031, 2308, 2353, 2513, 2584, 2796 and 2817 coming under PG II, IBCs shall be fitted with two shut-off devices.

罐柜运输要求

T3

T1-T22 本可移动罐柜导则适用于第1类和第3至9类液体和固体物质,须满足第4.2.1节的一般规定和第6.7.2节的要求。带 FRP 外壳的可移动罐柜导则适用于第 1、3、5.1、6.1、6.2、8 和 9 类或小类物质。此外,第 6.10 章的规定适用于带 FRP 外壳的可移动罐柜。 最小罐壳厚度底部开口最低试验 (单位: mm-标准安全减压规定a 规定b 可移动罐柜导则压力钢) (见第6.7.2.8 (见第6.7.2.6 (bar) (见第6.7.2.4 条) 条) 条) 2.65 见6.7.2.4.2 正常见6.7.2.6.2

S T1 – T22 These portable tank instructions apply to liquid and solid substances of class 1 and classes 3 to 9. The general provisions of section 4.2.1 and the requirements of section 6.7.2 shall be met. The instructions for portable tanks with FRP shells apply to substances of classes or divisions 1, 3, 5.1, 6.1, 6.2, 8 and 9. Additionally, the provisions of chapter 6.10 apply to the portable tanks with FRP shells. Minimum shell thickness Pressure relief Bottom opening (in mm – reference provisionsa provisionsb instruction pressure (bar) steel) (see 6.7.2.8) (see 6.7.2.6) (see 6.7.2.4) 2.65 See 6.7.2.4.2 Normal See 6.7.2.6.2

BK2

BK2 条文尚未录入本库。

罐柜特殊规定

TP33

为该物质指定的可移动罐柜导则适用于粒状和粉末状固体以及在高于其熔点的温度下装填和排放并作为固体块冷却和运输的固体。对于在高于其熔点的温度下运输的固体,见第4.2.1.19条。

The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point and which are cooled and transported as a solid mass. For solids which are transported above their melting point, see 4.2.1.19.

运输标签与标记

本货物包件应张贴以下标签与标记:

毒性物质 6.1 6.1
毒性物质 6.1

⚠ 海洋污染物(MP)须按本批货实际判定:本条目为未列明的泛指条目(N.O.S.),一览表第 4 栏未标 P 并不代表排除适用(2.10.2.4);按 2.10.2.5,如该批货特性符合第 2.9.3 节的海洋污染物标准,须作为海洋污染物运输并加贴 MP 标记。

本 UN 可按有限数量运输(一览表额度 500g);若本票按限量运输,须加贴 LQ 标记并符合第 3.4 章要求

本 UN 可按例外数量运输(代码 E4);若本票按例外数量运输,须加贴 EQ 标记并符合第 3.5 章要求

特殊规定(Special Provisions)

本条目适用特殊规定: 217274

SP 217

如果该物质在装载、包装或货物运输组件封闭时无明显的游离液体,不适用本《规则》的固体和有毒液体的混合物可按本条目运输,而不必首选适用第6.1类的分类标准。当用作散货容器时,每个货物运输组件须是防渗漏的。本条目不用于含有包装类I液体的固体物质。

This entry shall only be used for mixtures of solids which are not subject to the provisions of this Code and toxic liquids may be transported under this entry without first applying the classification criteria of class 6.1, provided there is no free liquid visible at the time the substance is loaded or at the time the packaging or cargo transport unit is closed. Each cargo transport unit shall be leakproof when used as a bulk container. This entry shall not be used for solids containing a packing group I liquid.

出处:IMDG Code 42-24 第 769 页

SP 274

运输单证和包装标记的正确运输名称须以技术名称作补充(见3.1.2.8.1)。 ■ 仅就UN 3077和UN 3082而言,技术名称可以是《危险货物一览表》第2栏中以大写字母显示的名称,条件是该名称不包括“N.O.S.”,且未指定特别规定274。 须使用最恰当地描述该物质或混合物的名称,例如: ■ UN 3082,环境有害物质,液体,未另列明(涂料) ■ UN 3082,环境有害物质,液体,未另列明(香水产品)。

For the purposes of documentation and package marking, the proper shipping name shall be supplemented with the technical name (see 3.1.2.8.1). For UN 3077 and UN 3082 only, the technical name may be a name shown in capital letters in column 2 of the Dangerous Goods List, provided that this name does not include “N.O.S.” and that special provision 274 is not assigned. The name which most appropriately describes the substance or mixture shall be used, e.g.: UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PAINT) UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERFUMERY PRODUCTS).

出处:IMDG Code 42-24 第 773 页

积载与隔离

积载与操作积载类B SW2(Category B SW2)
隔离一览表未列明隔离要求

积载操作代码(SW)

SW2

避开生活居住处所。

Clear of living quarters.

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