UN3375 硝酸铵乳液或悬浮液或凝胶，爆破炸药中间体

非敏感型乳胶、悬浮液和凝 胶，主要是硝酸铵和燃料的混 合物，该物质在使用前，进一 步加工以后可制成E型爆破炸 药。物质须满意的通过联合国 《实验与标准手册》第I部分 第18节实验系列8和主管当局 的认可。

Non-sensitized emulsions, suspensions and gels consisting primarily of a mixture of ammonium nitrate and fuel, intended to produce a Type E blasting explosive only after further processing prior to use. Substances shall satisfactorily pass test series 8 of the Manual of Tests and Criteria, part I, section 18 and be approved by the competent authority.

出处：IMDG Code 42-24 第 747 页

P505

P505 本导则适用于UN 3375 只要符合第4.1.1和4.1.3节的一般规定，允许使用下列包装： 组合包装最大容积/ 最大净重玻璃 5L 箱塑料 5L 铝 （4B） 125kg 金属 5L 天然木材，普通 （4C1） 125kg 天然木材，防筛墙 （4C2） 125kg 胶合板 （4D） 125kg 纤维板 （4G） 125kg 塑料，实心 （4H2） 125kg 桶铝，可拆卸桶顶 （1B2） 125kg 纤维 （1G） 125kg 其他金属 ， 可拆卸桶顶 125kg （1N2） 125kg 塑料，可拆卸桶顶 （1H2） 125kg 胶合板 （1D） 罐铝，可拆卸罐顶 （3B2） 125kg 塑料，可拆卸罐顶 （3H2） 125kg 单一包装桶铝（1B1、1B2） 250 L 塑料（1H1、1H2） 250 L 罐铝（3B1、3B2） 60 L 塑料（3H1、3H2） 60 L 复合包装塑料容器，外层为铝制桶（6HB1） 250 L P505 塑料容器，外层为纤维、塑料或胶合板桶（6HG1、6HH1、 250 L 6HD1） L 塑料容器，外层为铝制板条箱或箱子，或塑料容器，外层为木制、胶板、纤为板或硬塑料箱（6HB2、6HC、6HD2、6HG2、 6HH2） L 玻璃容器，外层为铝制、纤维、胶合板桶（6PB1、6PG1、 6PD1），或外层为泡沫塑料或实心塑料容器（6PH1、6PH2），或外层为铝制板条箱或箱子，或外层为木制或纤维板箱，或外层为藤条编织筐（6PB2、6PC、6PG2、6PD2）

P505 This instruction applies to UN 3375. The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met. △ Combination packagings Maximum capacity/ Glass 5 L Boxes Plastics 5 L aluminium (4B) 125 kg Metal 5 L natural wood, ordinary (4C1) 125 kg natural wood, sift-proof walls (4C2) 125 kg plywood (4D) 125 kg fibreboard (4G) 125 kg plastics, solid (4H2) 125 kg Drums aluminium, removable head (1B2) 125 kg fibre (1G) 125 kg other metal, removable head (1N2) 125 kg plastics, removable head (1H2) 125 kg plywood (1D) 125 kg Jerricans aluminium, removable head (3B2) 125 kg plastics, removable head (3H2) 125 kg Single packagings Drums aluminium (1B1, 1B2) 250 L plastics (1H1, 1H2) 250 L Jerricans aluminium (3B1, 3B2), 60 L plastics (3H1, 3H2) 60 L Composite packagings plastics receptacle with outer aluminium drum (6HB1) 250 L plastics receptacle with outer fibre, plastics or plywood drum 250 L (6HG1, 6HH1, 6HD1) plastics receptacle with outer aluminium crate or box or plastics receptacle with 60 L outer wooden, plywood, fibreboard or solid plastics box (6HB2, 6HC, 6HD2, 6HG2, 6HH2) glass receptacle with outer aluminium, fibre or plywood drum (6PB1, 6PG1, 6PD1) 60 L or with outer expanded plastics or solid plastics receptacles (6PH1, 6PH2) or with outer aluminium crate or box or with outer wooden or fibreboard box or with outer wickerwork hamper (6PB2, 6PC, 6PG2, 6PD2)

出处：IMDG Code 42-24 第 215 页（4.1.4.1）

IBC02

IBC02 只要符合第4.1.1、4.1.2和4.1.3节的一般规定，允许使用下列IBCs： 金属（31A、31B和31N）； 硬质塑料（31H1和31H2）； 复合包装（31HZ1）。 特殊包装规定： B5 对于盛装UN 1791、2014、2984和3149的IBCs，须配备允许在运输过程中排气的装置。排气装置的入口须设在运输过程中IBC最大充装条件下的蒸气空间内。 B8 纯物质不得使用 IBCs 运输，因为已知该物质在 50°C蒸汽压超过 110kPa，在 55°C时蒸气压超过130kPa。 B15 对于硝酸含量超过 55%的UN 2031，硬质塑料 IBCs和复合IBCs的硬质塑料内容器的允许使用期限为生产日期起两年。 B16 对于UN3375，未经主管当局批准，不得使用31A和31N型的IBCs。 B20 对于包装类II的UN 1716、1717、1736、1737、1738、1742、1743、1755、1764、 1768、1776、1778、1782、1789、1790、1796、1826、1830、1832、2031、 2308、2353、2513、2584、2796和2817，IBCs须安装两个关闭装置。

IBC02 The following IBCs are authorized, provided the general provisions of 4.1.1, 4.1.2 and 4.1.3 are met: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Special packing provisions: B5 For UN Nos. 1791, 2014, 2984 and 3149, IBCs shall be provided with a device to allow venting during transport. The inlet to the venting device shall be sited in the vapour space of the IBC under maximum filling conditions during transport. B8 The pure form of this substance shall not be transported in IBCs since it is known to have a vapour pressure of more than 110 kPa at 50C or 130 kPa at 55C. ° ° B15 For UN 2031 with more than 55% nitric acid, the permitted use of rigid plastics IBCs and of rigid plastics inner receptacles of composite IBCs shall be two years from their date of manufacture. B16 For UN 3375, IBCs of type 31A and 31N are not allowed without competent authority approval. B20 For UN Nos. 1716, 1717, 1736, 1737, 1738, 1742, 1743, 1755, 1764, 1768, 1776, 1778, 1782, 1789, 1790, 1796, 1826, 1830, 1832, 2031, 2308, 2353, 2513, 2584, 2796 and 2817 coming under PG II, IBCs shall be fitted with two shut-off devices.

T1

T1-T22 本可移动罐柜导则适用于第1类和第3至9类液体和固体物质，须满足第4.2.1节的一般规定和第6.7.2节的要求。带 FRP 外壳的可移动罐柜导则适用于第 1、3、5.1、6.1、6.2、8 和 9 类或小类物质。此外，第 6.10 章的规定适用于带 FRP 外壳的可移动罐柜。 最小罐壳厚度底部开口最低试验 （单位: mm-标准安全减压规定a 规定b 可移动罐柜导则压力钢） （见第6.7.2.8 （见第6.7.2.6 （bar） （见第6.7.2.4 条） 条） 条） 1.5 见6.7.2.4.2 正常见6.7.2.6.2

S T1 – T22 These portable tank instructions apply to liquid and solid substances of class 1 and classes 3 to 9. The general provisions of section 4.2.1 and the requirements of section 6.7.2 shall be met. The instructions for portable tanks with FRP shells apply to substances of classes or divisions 1, 3, 5.1, 6.1, 6.2, 8 and 9. Additionally, the provisions of chapter 6.10 apply to the portable tanks with FRP shells. Minimum shell thickness Pressure relief Bottom opening (in mm – reference provisionsa provisionsb instruction pressure (bar) steel) (see 6.7.2.8) (see 6.7.2.6) (see 6.7.2.4) 1.5 See 6.7.2.4.2 Normal See 6.7.2.6.2

不得超过第4.2.1.9.条中规定的充灌度。

The degree of filling prescribed in 4.2.1.9.2 shall not be exceeded.

本描述下运输的物质只能在主管当局批准的可移动罐柜中运输。

A substance under this description shall only be transported in a portable tank under an approval granted by the competent authority.

罐柜的隔热材料只能使用无机不易燃材料。

Only inorganic non-combustible materials shall be used for thermal insulation of the tank.

对于UN 0331、0332和3375，可移动罐柜可在下列条件下使用：.1 为避免不必要的气封，每个由金属或纤维增强塑料制成的可移动罐柜均须安装减压装置，该装置可以是弹簧式重闭装置、保险片或易熔元件。对于最小试验压力大于 4bar 的可移动罐柜，其排放压力或起动压力（视情而定）不得大于2.65 bar。.2 仅对 UN 3375，须证明其适合在罐柜中运输。评估此适用性的一种方法是试验系列 8 中的试验 8（d）（见《试验和标准手册》第 1 部分第 18.7小节）。.3 不得让物质在可移动罐柜中停留太长时间，一面结块。须采取适当措施避免物质在可移动罐柜中积聚和堆积（例如清洁等）。

For UN Nos. 0331, 0332 and 3375, portable tanks may be used subject to the following conditions:.1 To avoid unnecessary confinement, each portable tank constructed of metal or fibre-reinforced plastics shall be fitted with a pressure relief device that may be of the re-closing spring-loaded type, a frangible disc or a fusible element. The set-to-discharge or burst pressure, as applicable, shall not be greater than 2.65 bar for portable tanks with minimum test pressures greater than bar..2 F or UN 3375 only, suitability for transport in tanks shall be demonstrated. One method to evaluate this suitability is test 8 (d) in Test Series 8 (see Manual of Tests and Criteria, part 1, subsection 18.7)..3 Substances shall not be allowed to remain in the portable tank for any period that could result in caking. Appropriate measures shall be taken to avoid accumulation and packing of substances in the tank (e.g. cleaning, etc).

SP 309

本条目适用于主要成份由硝酸铵与燃料混合物构成的未敏化乳胶、悬浮体或凝胶，拟用于在使用之前进一步加工生产成E型爆破炸药。 典型的乳胶成分如下：60-85%的硝酸铵、5-30%的水、2-8%燃料、0.5- 4%乳化剂、0-10%可溶防燃剂和微量添加剂。其他无机硝酸盐可以代替部分硝酸铵。 典型的悬浮体和凝胶成分如下：60-85%的硝酸铵、0-5%过氯酸钠或钾、 0-17%硝酸环六亚甲基四胺或硝酸甲基胺、5-30%水、2-15%燃料、0.5- 4%增厚剂、0-10%可溶防燃剂和微量添加剂。其他无机硝酸盐可以代替部分硝酸铵。 这些物质须符合《试验和标准手册》第I部分第18节系列试验8的硝酸铵乳剂、悬浮液或凝胶、爆破炸药中间物(ANE)的分类标准，并经主管当局批准。

This entry applies to non-sensitized emulsions, suspensions and gels consisting primarily of a mixture of ammonium nitrate and fuel, intended to produce a Type E blasting explosive only after further processing prior to use. The mixture for emulsions typically has the following composition: 60–85% ammonium nitrate, 5–30% water, 2–8% fuel, 0.5–4% emulsifier agent, 0–10% soluble flame suppressants, and trace additives. Other inorganic nitrate salts may replace part of the ammonium nitrate. The mixture for suspensions and gels typically has the following composition: 60–85% ammonium nitrate, 0–5% sodium or potassium perchlorate, 0–17% hexamine nitrate or monomethylamine nitrate, 5–30% water, 2–15% fuel, 0.5–4% thickening agent, 0–10% soluble flame suppressants, and trace additives. Other inorganic nitrate salts may replace part of the ammonium nitrate. Substances shall satisfy the criteria for classification as an ammonium nitrate emulsion, suspension or gel, intermediate for blasting explosives (ANE) of Test Series 8 of the Manual of Tests and Criteria, part I, section 18 and be approved by the competent authority.

出处：IMDG Code 42-24 第 776 页

避开热源。

Protected from sources of heat.

2 氨化合物类

2 ammonium compounds

与第4.1类“隔离”。

Stow “separated from” class 4.1.

与SGG3 - 溴酸盐“隔离”。

Stow “separated from” SGG3 – bromates.

与氯酸盐类“隔离”。

Stow “separated from” SGG4 – chlorates.

与SGG5 - 亚氯酸盐类“隔离”。

Stow “separated from” SGG5 – chlorites.

与可燃材料（特别是液体）“隔离”。

Stow “separated from” combustible material (particularly liquids).

与次氯酸盐“隔离”。

Stow “separated from” SGG8 – hypochlorites.

与SGG12 - 亚硝酸盐“隔离”。

Stow “separated from” SGG12 – nitrites.

与SGG13 - 高氯酸盐“隔离”。

Stow “separated from” SGG13 – perchlorates.

与SGG14 - 高锰酸盐“隔离”。

Stow “separated from” SGG14 – permanganates.

与SGG15 - 金属粉末“隔离”。

Stow “separated from” SGG15 – powdered metals.