UN3479 燃料电池筒或设备中含有燃料电池筒或与设备合装在一起的燃料电池筒，在金属氢化物内含有氢

含有远比空气轻的氢气、丁烷 或其他易燃无味气体的燃料电 池筒，也可以在设备中或与设 备合装在一起运输

Fuel cell cartridges containing hydrogen, butane or other flammable odourless gas, which is much lighter than air, may also be shipped in or packed with equipment.

出处：IMDG Code 42-24 第 757 页

P004

P004 本导则适用于UN 3473、UN 3476、UN 3477、UN 3478和UN 3479。 允许使用以下包装： （1） 对于燃料电池盒，须符合第 4.1.1.1、4.1.1.2、4.1.1.3、4.1.1.6 条和第 4.1.3 节的一般规定： 桶（1A2、1B2、1N2、1H2、1D、1G）； 箱（4A、4B、4N、4C1、4C2、4D、4F、4G、4H1、4H2）； 罐（3A2、3B2、3H2）； P004 包装须符合包装类II的性能水平。 （2） 与设备一起包装的燃料电池盒：符合第4.1.1.1、4.1.1.2、4.1.1.6条和第4.1.3节一般规定的坚固外包装。 当燃料电池盒与设备一起包装时, 须将其装入内包装中或放置在外包装中，并加垫材料或隔板，以保护燃料电池盒免受因外包装内物品移动或放置位置而造成的损坏。 设备须固定在外包装内以防止移动。 对于本包装导则而言，“设备”是指需要与其一起包装的燃料电池盒才能运行的设备。 （3） 对于设备中的燃料电池盒，符合第4.1.1.1、4.1.1.2、4.1.1.6条和第4.1.3节一般规定的坚固外包装。 装有燃料电池盒的大型坚固设备（见第 4.1.3.8 条）可以无包装运输。对于设备中的燃料电池盒，整个系统须受到保护，以防止短路和意外操作。 注：（2）和（3）中允许的包装净重可以超过 400 kg（见第4.1.3.3条）。

P004 This instruction applies to UN Nos. 3473, 3476, 3477, 3478 and 3479. The following packagings are authorized: (1) For fuel cell cartridges, provided that the general provisions of 4.1.1.1, 4.1.1.2, 4.1.1.3, 4.1.1.6 and 4.1.3 are met: Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A2, 3B2, 3H2). Packagings shall conform to the packing group II performance level. (2) For fuel cell cartridges packed with equipment: strong outer packagings which meet the general provisions of 4.1.1.1, 4.1.1.2, 4.1.1.6 and 4.1.3. When fuel cell cartridges are packed with equipment, they shall be packed in inner packagings or placed in the outer packaging with cushioning material or divider(s) so that the fuel cell cartridges are protected against damage that may be caused by the movement or placement of the contents within the outer packaging. The equipment shall be secured against movement within the outer packaging. For the purpose of this packing instruction, “equipment” means apparatus requiring the fuel cell cartridges with which it is packed for its operation. (3) For fuel cell cartridges contained in equipment: strong outer packagings which meet the general provisions of 4.1.1.1, 4.1.1.2, 4.1.1.6 and 4.1.3. Large robust equipment (see 4.1.3.8) containing fuel cell cartridges may be transported unpackaged. For fuel cell cartridges contained in equipment, the entire system shall be protected against short circuit and inadvertent operation. Note: The packagings authorized in (2) and (3) may exceed a net mass of 400 kg (see 4.1.3.3).

出处：IMDG Code 42-24 第 173 页（4.1.4.1）

SP 328

本条目适用于燃料电池筒，包括包含在设备内或与设备合装在一起的燃料电池。安装在燃料电池系统内或构成其整体一部分的燃料电池筒被认为是包含在设备之中。“燃料电池筒”系指储存燃料并通过阀门控制将燃料释放至燃料电池中的物品。燃料电池筒，包括安装在设备中的燃料电池筒，须在设计和制造上防止在正常运输条件下燃料发生泄露。 使用液体作为燃料的燃料电池筒设计类型须通过100kPa(测量)的内压试验而不发生泄露。 除符合特别规定339的在金属氢化合物中储氢的燃料电池筒外，每个燃料电池筒设计类型须表明能够通过在最能破坏其盛装系统方向上，向坚硬表面的1.2米的跌落试验，且内容物无损失。 当燃料电池系统内装有锂金属、锂离子或钠离子电池时，该批货物须按此条目托运，并按 UN 3091 设备内装有锂金属电池、UN 3481 设备内装有锂离子电池或 UN 3552 设备内装有钠离子电池的相应条目托运。

This entry applies to fuel cell cartridges, including when contained in equipment or packed with equipment. Fuel cell cartridges installed in or integral to a fuel cell system are regarded as contained in equipment. “Fuel cell cartridge” means an article that stores fuel for discharge into the fuel cell through a valve(s) that controls the discharge of fuel into the fuel cell. Fuel cell cartridges, including when contained in equipment, shall be designed and constructed to prevent fuel leakage under normal conditions of transport. Fuel cell cartridge design types using liquids as fuels shall pass an internal pressure test at a pressure of 100 kPa (gauge) without leakage. Except for fuel cell cartridges containing hydrogen in metal hydride, which shall be in compliance with special provision 339, each fuel cell cartridge design type shall be shown to pass a 1.2 m drop test onto an unyielding surface, in the orientation most likely to result in failure of the containment system, with no loss of contents. When lithium metal, lithium ion or sodium ion batteries are contained in the fuel cell system, the consignment shall be consigned under this entry and under the appropriate entries for UN 3091 LITHIUM METAL BATTERIES CONTAINED IN EQUIPMENT, UN 3481 LITHIUM ION BATTERIES CONTAINED IN EQUIPMENT or UN 3552 SODIUM ION BATTERIES CONTAINED IN EQUIPMENT.

出处：IMDG Code 42-24 第 777 页

SP 339

在本条目下运输的含有在金属氢化合物内的氢的燃料电池筒的水容量须少于或等于120 mL 。燃料电池筒内的压力在55℃时须不超过5 MPa。设计类型须承受在55°C 时两倍于燃料筒设计压力或在55°C 时大于燃料筒设计压力200 kPa，以较大者为准，不发生泄露或爆裂。进行此项试验的压力是跌落试验和氢循环试验中所指的“最低壳爆裂压力”。 燃料电池筒须按照制造商提供的程序充灌。生产商须对每个燃料电池筒提供以下信息：.1 燃料电池筒首次充灌之前和再次充灌之前应进行的检查程序；.2 需了解的安全防范和潜在的危险；.3 确定达到额定容量的方法；.4 最小和最大压力范围：.5 最小和最大温度范围；和.6 首次充灌和再次充灌应满足的任何其他要求，包括首次充灌和再次充灌使用的设备。 燃料电池筒须在设计和制造上防止在正常运输条件下燃料发生泄露。每个燃料筒的设计类型，包括作为燃料电池整体的燃料筒，须进行并通过以下试验： 跌落试验在1.8米高度从四个不同方向对一个坚硬表面的跌落试验：.1 垂直方向，在装有截止阀部件的一端；.2 垂直方向，在装有截止阀部件相反的一端；.3 水平方向，跌落至一个直径为38 mm的钢制尖端体，钢尖位置向上； 和 4 45°角方向，在装有截止阀部件的一端。 燃料筒被充灌至额定充灌压力时，采用肥皂泡沫溶液对所有可能泄漏的位置进行测试确定无任何泄漏。燃料电池筒然后须进行静水压力破坏。所记录的爆裂压力须超过最低壳爆裂压力的85%。 火烧试验用氢充灌至额定容量的燃料电池筒须进行火烧试验。燃料筒设计，可带有作为其整体一部分的通气装置，可认为已通过火烧试验，如果满足以下条件：.1 内部压力通过通气装置排至零表压而燃料筒无破裂；或.2 燃料筒在火中坚持至少20分钟而不破裂。 氢循环试验本试验旨在于保证燃料电池筒在使用过程中不会超过其设计应力。 燃料电池筒的循环试验须从不超过5%额定容量至不少于95%额定容量并且再回到不超过5%额定氢容量。 须使用额定充灌压力来进行充灌并且温度须被保持在操作温度的范围内。 该循环须连续进行至少100次。 在循环试验后，燃料电池筒须进行充灌并且须对燃料电池筒的排水量进行测量。如果受试燃料电池筒的排水量不超过未受试的，充灌至95%额定容量并加压至其最低壳爆裂压力的75%的燃料电池筒的排水量，则认为通过循环试验。 产品泄漏试验每个燃料电池筒须在15℃±5℃加压至额定充灌压力下进行泄漏试验。须使用肥皂泡沫溶液或其他等同方法对所有可能发生泄漏的位置确定无泄漏出现。 每个燃料电池筒须永久性地标记以下信息：.1 以兆帕(MPa)表示的充灌压力；.2 生产商的燃料电池筒系列编号或独特的识别编号；和.3 基于最大使用寿命的失效日期(以四位数表示年，两位数表示月)。

Fuel cell cartridges containing hydrogen in a metal hydride transported under this entry shall have a water capacity less than or equal to 120 mL. The pressure in the fuel cell cartridge shall not exceed 5 MPa at 55C. The design type shall withstand, without leaking or bursting, a pressure of two (2) ° times the design pressure of the cartridge at 55C or 200 kPa more than the design pressure of the ° cartridge at 55C, whichever is greater. The pressure at which this test is conducted is referred to in ° the Drop Test and the Hydrogen Cycling Test as the “minimum shell burst pressure”. Fuel cell cartridges shall be filled in accordance with procedures provided by the manufacturer. The manufacturer shall provide the following information with each fuel cell cartridge:.1 Inspection procedures to be carried out before initial filling and before refilling of the fuel cell cartridge;.2 Safety precautions and potential hazards to be aware of;.3 Method for determining when the rated capacity has been achieved;.4 Minimum and maximum pressure range;.5 Minimum and maximum temperature range; and.6 Any other requirements to be met for initial filling and refilling, including the type of equipment to be used for initial filling and refilling. The fuel cell cartridges shall be designed and constructed to prevent fuel leakage under normal conditions of transport. Each cartridge design type, including cartridges integral to a fuel cell, shall be subjected to and shall pass the following tests: Drop test A 1.8 m drop test onto an unyielding surface in four different orientations:.1 Vertically, on the end containing the shut-off valve assembly;.2 Vertically, on the end opposite to the shut-off valve assembly;.3 Horizontally, onto a steel apex with a diameter of 38 mm, with the steel apex in the upward position; and.4 At a 45 angle on the end containing the shut-off valve assembly. ° There shall be no leakage, determined by using a soap bubble solution or other equivalent means on all possible leak locations, when the cartridge is charged to its rated charging pressure. The fuel cell cartridge shall then be hydrostatically pressurized to destruction. The recorded burst pressure shall exceed 85% of the minimum shell burst pressure. Fire test A fuel cell cartridge filled to rated capacity with hydrogen shall be subjected to a fire engulfment test. The cartridge design, which may include a vent feature integral to it, is deemed to have passed the fire test if:.1 The internal pressure vents to zero gauge pressure without rupture of the cartridge; or.2 The cartridge withstands the fire for a minimum of 20 minutes without rupture. Hydrogen cycling test This test is intended to ensure that a fuel cell cartridge design stress limits are not exceeded during use. The fuel cell cartridge shall be cycled from not more than 5% rated hydrogen capacity to not less than 95% rated hydrogen capacity and back to not more than 5% rated hydrogen capacity. The rated charging pressure shall be used for charging and temperatures shall be held within the operating temperature range. The cycling shall be continued for at least 100 cycles. Following the cycling test, the fuel cell cartridge shall be charged and the water volume displaced by the cartridge shall be measured. The cartridge design is deemed to have passed the hydrogen cycling test if the water volume displaced by the cycled cartridge does not exceed the water volume displaced by an uncycled cartridge charged to 95% rated capacity and pressurized to 75% of its minimum shell burst pressure. Production leak test Each fuel cell cartridge shall be tested for leaks at 15C 5C, while pressurized to its rated charging ° ± ° pressure. There shall be no leakage, determined by using a soap bubble solution or other equivalent means on all possible leak locations. Each fuel cell cartridge shall be permanently marked with the following information:.1 The rated charging pressure in megapascals (MPa);.2 The manufacturer’s serial number of the fuel cell cartridges or unique identification number; and.3 The date of expiry based on the maximum service life (year in four digits; month in two digits).

出处：IMDG Code 42-24 第 777 页