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UN1408 硅铁,含硅不小于 30%,小于90%

FERROSILICON with 30% or more but less than 90% silicon

IMDG Code 42-24 第4.3类 包装类别 III 更新 2026-09-08

基本信息

UN 编号UN1408
中文名称硅铁,含硅不小于 30%,小于90%
英文名称FERROSILICON with 30% or more but less than 90% silicon
危险类别第4.3类(副危险 6.1)
包装类别III
海洋污染物
有限数量1 kg
例外数量E1
EmS 应急措施F-G,S-N(F-G, S-N)

物质性质与外观

与潮气、水、碱类或酸类接触 放出易燃的能与空气形成爆炸 性的混合物的气体氢气,以及 剧毒性的砷和磷化氢气体。这 些气体在机械通风的条件下其 毒性远超过爆炸危险。气体从 货物表面新破裂处释放的速度 最大。装货中当货物被搅动 时,气体释放速度增加。吞 咽、与皮肤接触或吸入蒸气会 中毒。

In contact with moisture, water, alkalis or acids, may evolve hydrogen, a flammable gas, which may form explosive mixtures with air, and also arsine and phosphine, which are highly toxic gases. These gases are evolved in proportions which, under mechanically ventilated conditions, make the poison hazard by far predominant over the explosion hazard. The rate of gas evolution is greatest from freshly broken surfaces, so is liable to increase whenever the cargo is disturbed, such as during loading. Toxic if swallowed, by skin contact or by vapour inhalation.

出处:IMDG Code 42-24 第 630 页

包装要求

本条目适用的包装导则: P003 ;有限数量 1 kg,例外数量 E1。

P003

P003 危险货物须置于合适的外包装中。内包装须符合第 4.1.1.1、4.1.1.2、4.1.1.4、4.1.1.8 条和第4.1.3节的规定,其设计须符合第6.1.4节的构造规定。须使用由合适材料制成的外包装, 其强度和设计须与包装容量和预期用途相称。当本导则规则用于物品或组合包装内容器的运输时,包装的的设计和构造须防止物品在正常运输条件下意外筛漏。 特殊包装规定: PP16 对于UN 2800,须防止电池在包装内短路。 PP17 对于 UN 2037,纤维板包装的包件的净重不得超过 55 kg,其他包装的包件净重不得超过125 kg。 PP18 对于 UN 1845,包装的设计和构造须允许释放二氧化碳气体,以防止压力积聚导致包装破裂。 PP19 对于UN 1327、1364、1365、1856和3360,允许以捆包形式运输。 PP20 对于UN 1363、1386、1408、2793,可以使用任何防筛漏、防撕裂容器。 PP32 对于 UN 2857、3358 以及根据 UN 3164托运的坚固物品,可以不包装,装在板条箱或适当的外包装中运输。 注:批准的包装净重可超过 400 千克(见第4.1.3.3条)。 PP90 对于 UN 3506 和 3354,须使用密封的内衬或袋子,内衬和袋子由坚固的防漏、防刺穿材料制成,这些材料不透汞或镓,视情而定,无论包装处于何种位置,都能防止物质从包件中漏出。 PP91 对于 UN1044,大型灭火器也可无包装运输,但前提是满足第 4.1.3.8.1.1 至 4.1.3.8.1.5条的规定,阀门采用第 4.1.6.1.8.1至 4.1.6.1.8.4中规定的任一方法进行防护,且安装在灭火器上的其他设备受到保护,以防止意外启动。就本特殊包装规定而言,“大型灭火器”系指第3.3章特殊规定225第.3至.5款中描述的灭火器。 PP96 对于根据特殊规定327运输的UN 2037废气罐,包装须充分通风,以防止产生危险气氛和压力积聚。 PP100 对于 UN1408 和 2793,柔性、纤维板或木质包装须防筛漏和防水,或须装有防筛漏和防水衬里。

P003 Dangerous goods shall be placed in suitable outer packagings. The packagings shall meet the provisions of 4.1.1.1, 4.1.1.2, 4.1.1.4, 4.1.1.8 and 4.1.3 and be so designed that they meet the construction provisions of 6.1.4. Outer packagings constructed of suitable material, and of adequate strength and design in relation to the packaging capacity and its intended use, shall be used. Where this packing instruction is used for the transport of articles or inner packagings of combination packagings, the packaging shall be designed and constructed to prevent inadvertent discharge of articles during normal conditions of transport. Special packing provisions: PP16 For UN 2800, batteries shall be protected from short circuit within the packagings. PP17 For UN 2037, packages shall not exceed 55 kg net mass for fibreboard packagings or 125 kg net mass for other packagings. PP18 For UN 1845, packagings shall be designed and constructed to permit the release of carbon dioxide gas to prevent a build-up of pressure that could rupture the packagings. PP19 For UN Nos. 1327, 1364, 1365, 1856 and 3360, transport as bales is authorized. PP20 For UN Nos. 1363, 1386, 1408 and 2793, any sift-proof, tearproof receptacle may be used. PP32 UN Nos. 2857 and 3358 and robust articles consigned under UN 3164 may be transported unpackaged, in crates or in appropriate overpacks. Note: The packagings authorized may exceed a net mass of 400 kg (see 4.1.3.3). PP90 For UN Nos. 3506 and 3554, sealed inner liners or bags of strong leakproof and puncture resistant material impervious to mercury or gallium, as appropriate, which will prevent escape of the substance from the package irrespective of the position of the package shall be used. PP91 For UN 1044, large fire extinguishers may also be transported unpackaged provided that the requirements of 4.1.3.8.1.1 to 4.1.3.8.1.5 are met, the valves are protected by one of the methods in accordance with 4.1.6.1.8.1 to 4.1.6.1.8.4 and other equipment mounted on the fire extinguisher is protected to prevent accidental activation. For the purpose of this special packing provision, “large fire extinguishers” means fire extinguishers as described in subparagraphs.3 to.5 of special provision 225 of chapter 3.3. PP96 For UN 2037 waste gas cartridges transported in accordance with special provision 327, the packagings shall be adequately ventilated to prevent the creation of dangerous atmospheres and the build-up of pressure. PP100 For UN Nos. 1408 and 2793 flexible, fibreboard or wooden packagings shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-resistant liner.

出处:IMDG Code 42-24 第 173 页(4.1.4.1)

包装特殊规定

PP20

对于UN 2217,可以使用防筛漏、防撕裂的容器。

For UN 2217, any sift-proof, tearproof receptacle may be used.

PP100

对于 UN1309、1323、1333、1376、1435、1449、1457、1472、1476、1483、 1509、1516、1567、1869、2210、2858、2878、2968、3089、3096 和 3125,软质、纤维板或木质容器须防筛漏和防水,或须具有防筛漏和防水的内衬。

For UN numbers 1309, 1323, 1333, 1376, 1435, 1449, 1457, 1472, 1476, 1483, 1509, 1516, 1567, 1869, 2210, 2858, 2878, 2968, 3089, 3096 and 3125, flexible, fibreboard or wooden packagings shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-resistant liner.

中型散装容器(IBC)要求

IBC08

IBC08 只要符合第4.1.1、4.1.2和4.1.3节的一般规定,允许使用下列IBCs: 金属(11A、11B、11N、21A、21B、21N、31A、31B 和 31N); 硬质塑料(11H1、11H2、21H1、21H2、31H1 和 31H2); 复合包装(11HZ1、11HZ2、21HZ1、21HZ2 和 31HZ1); 纤维板(11G); 木质包装(11C、11D和11F); 软质包装(13H1、13H2、13H3、13H4、13H5、13L1、13L2、13L3、13L4、13M1 IBC08 或13M2)。 补充规定: 如果在运输期间固体变成液体,请参见第4.1.3.4条。 特殊包装规定: B3 软质IBCs须防筛漏和防水,或装配防筛漏和防水内衬。 B4 软质、纤维板或木制IBCs须防筛漏和防水,或配备防筛漏和防水内衬。 B6 对于 UN 1327、1363、1364、1365、1386、1408、1841、2211、2217、2793 和 3314的IBCs,无需满足第6.5章的IBCs试验要求。 B21 除了金属或硬质塑料 IBCs,对于盛装固体物质的 IBCs 须装在封闭货物运输组件或货运集装箱/货运车辆内运输,货物运输组件或货运集装箱/货运车辆须具有至少与IBCs高度相同的硬质侧壁或围栏。

IBC08 The following IBCs are authorized, provided the general provisions of 4.1.1, 4.1.2 and 4.1.3 are met: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2 and 31HZ1); Fibreboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2). Additional provisions: Where the solid may become liquid during transport see 4.1.3.4. Special packing provisions: B3 Flexible IBCs shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-resistant liner. B4 Flexible, fibreboard or wooden IBCs shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-resistant liner. B6 For UN Nos. 1327, 1363, 1364, 1365, 1386, 1408, 1841, 2211, 2217, 2793 and 3314, IBCs are not required to meet the IBC testing provisions of chapter 6.5. B21 For solid substances in IBCs other than metal or rigid plastics IBCs, the IBCs shall be carried in closed cargo transport units or in freight containers/vehicles, which shall have rigid sides or fences at least to the height of the IBC.

罐柜运输要求

T1

T1-T22 本可移动罐柜导则适用于第1类和第3至9类液体和固体物质,须满足第4.2.1节的一般规定和第6.7.2节的要求。带 FRP 外壳的可移动罐柜导则适用于第 1、3、5.1、6.1、6.2、8 和 9 类或小类物质。此外,第 6.10 章的规定适用于带 FRP 外壳的可移动罐柜。 最小罐壳厚度底部开口最低试验 (单位: mm-标准安全减压规定a 规定b 可移动罐柜导则压力钢) (见第6.7.2.8 (见第6.7.2.6 (bar) (见第6.7.2.4 条) 条) 条) 1.5 见6.7.2.4.2 正常见6.7.2.6.2

S T1 – T22 These portable tank instructions apply to liquid and solid substances of class 1 and classes 3 to 9. The general provisions of section 4.2.1 and the requirements of section 6.7.2 shall be met. The instructions for portable tanks with FRP shells apply to substances of classes or divisions 1, 3, 5.1, 6.1, 6.2, 8 and 9. Additionally, the provisions of chapter 6.10 apply to the portable tanks with FRP shells. Minimum shell thickness Pressure relief Bottom opening (in mm – reference provisionsa provisionsb instruction pressure (bar) steel) (see 6.7.2.8) (see 6.7.2.6) (see 6.7.2.4) 1.5 See 6.7.2.4.2 Normal See 6.7.2.6.2

BK2

BK2 条文尚未录入本库。

罐柜特殊规定

TP33

为该物质指定的可移动罐柜导则适用于粒状和粉末状固体以及在高于其熔点的温度下装填和排放并作为固体块冷却和运输的固体。对于在高于其熔点的温度下运输的固体,见第4.2.1.19条。

The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point and which are cooled and transported as a solid mass. For solids which are transported above their melting point, see 4.2.1.19.

运输标签与标记

本货物包件应张贴以下标签与标记:

遇水放出易燃气体 4.3 4.3
遇水放出易燃气体 4.3
毒性物质 6.1 6.1
毒性物质 6.1

本 UN 可按有限数量运输(一览表额度 1kg);若本票按限量运输,须加贴 LQ 标记并符合第 3.4 章要求

本 UN 可按例外数量运输(代码 E1);若本票按例外数量运输,须加贴 EQ 标记并符合第 3.5 章要求

特殊规定(Special Provisions)

本条目适用特殊规定: 39223932

SP 39

当这种物质含有小于30%或不小于90%的硅时,不适用本规则的规定。

This substance, when it contains less than 30% or not less than 90% silicon, is not subject to the provisions of this Code.

出处:IMDG Code 42-24 第 765 页

SP 223

如果在测试时物质所表现的化学或物理特性不满足第3栏中所列类别或任何其他类别已建立的定义标准,除了2.10.3适用的海洋污染物以外,则不适用本《规则》的规定。

If the chemical or physical properties of a substance covered by this description are such that, when tested, it does not meet the established defining criteria for the class or division listed in column 3, or any other class or division, it is not subject to the provisions of this Code except in the case of a marine pollutant where 2.10.3 applies.

出处:IMDG Code 42-24 第 770 页

SP 932

要求制造商或托运人出具证明,说明货物在装运前以包装尺寸在隐蔽下但在露天存放了至少3天。

Requires a certificate from the maker or shipper, stating that the shipment was stored under cover, but in the open air, in the size in which it was packaged, for not less than 3 days prior to shipment.

出处:IMDG Code 42-24 第 793 页

积载与隔离

积载与操作积载类A SW2 SW5 H1(Category A SW2 SW5 H1)
隔离SG26 SG35 SG36

积载操作代码(SW)

SW2

避开生活居住处所。

Clear of living quarters.

SW5

若在舱内,在机械通风处积载。

If under deck, stow in a mechanically ventilated space.

隔离代码(7.2.8)

SG26

补充:当在集装箱船上舱面积载时,须在横向与第 2.1 类和第 3 类保持最小两个箱位,当在滚装船上积载时,须在横向与第 2.1 类和第 3 类保持最小6米。

In addition: from goods of classes 2.1 and 3 when stowed on deck of a containership a minimum distance of two container spaces athwartship shall be maintained, when stowed on ro-ro ships a distance of 6 m athwartship shall be maintained.

SG35

与SGG1 - 酸类“隔离”。

Stow “separated from” SGG1 – acids.

SG36

与SGG18 - 碱类“隔离”。

Stow “separated from” SGG18 – alkalis.

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