UN3228 E型自反应固体

高温或遇火会分解，猛烈燃 烧。不溶解于水。遇到碱类或 酸类会引起危险的分解，吸入 燃烧或自行分解的产物会中 毒。

Decomposes at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation.

出处：IMDG Code 42-24 第 733 页

P520

P520 本导则适用于第5.2类有机过氧化物和第4.1类自反应物质只要符合第4.1.1和4.1.3节的一般规定和第4.1.7节的特殊规定，允许使用下列包装： 包装方法为OP1至OP8。第2.4.2.3.2.3和2.5.3.2.4条列出了适合于当前指定的有机过氧化物和自反应物质的包装方法。每种包装方法规定的数量每个包件允许的最大数量。允许使用下列包装： （1） 组合包装，其外包装由箱（4A、4B、4N、4C1、4C2、4D、4F、4G、4H1和 4H2）、桶（1A1、1A2、1B1、1B2、1G、1H1、1H2和1D）和罐（3A1、3A2、 3B1、3B2、3H1和3H2）组成； （2） 单一包装，由桶（1A1、1A2、1B1、1B2、1G、1H1、1H2和1D）和罐（3A1、 3A2、3B1、3B2、3H1和3H2）组成； （3） 带有塑料内包装的复合包装（6HA1、6HA2、6HB1、6HB2、6HC、6HD1、6HD2、 6HG1、6HG2、6HH1和6HH2）。 包装方法OP1至OP8的每种包装/包裹的最大装量为： 包装方法 OP1 OP21 OP3 OP41 OP5 OP6 OP7 OP8 最大装量固体和组合包装 （液体和固体）的 0.5 0.5/10 5 5/25 25 50 50 4002 最大重量（kg） 液体的最大容量3 0.5 - 5 - 30 60 60 2254 如果有两个数值，第一个数值适用于每个内包装的最大净重，第二个数值适用于整个包件的最大净重。 P520 罐为 60 kg/箱为 200 kg，对于固体，在外包装为箱（4C1、4C2、4D、4F、4G、4H1、 4H2）的组合包装中，以及在内包装为塑料或纤维且最大净重为 25kg 的组合包装中， 为400 kg。 粘性液体如不符合第1.2.1节中液体定义所规定的标准，则须作为固体处理。 罐为60L。 补充规定： 金属包装，包括组合包装的内包装和组合包装或复合包装的外包装，只能用于包装方法 OP7和OP8。 在组合包装中，玻璃容器只能用作内包装，固体的最大容量为 0.5 kg，液体的最大容量为0.5 L。 组合包装中衬垫材料不得易燃。 需贴有爆炸性副危险性标志（图例 No.1,见第 5.2.2.2.2 条）的有机过氧化物或自反应物质的包装还须符合第4.1.5.10和4.1.5.11条的规定。 特殊包装规定： PP21 对某些 B 类或 C 类自反应物质，即 UN 3221、3222、3223、3224、3231、3232、 3233 和 3234，须使用比包装方法 OP5 或 OP6 分别允许的更小容器的包装（见第 4.1.7节和第2.4.2.3.2.3条）。 PP22 UN 3241，2-溴-2-硝基丙烷-1,3-二醇，须按照包装方法OP6包装。 PP94 第2.0.4.3条中极少量的高能样品可酌情按 UN 3223 或 UN 3224 运输，但须满足以下条件：.1 仅使用由箱（4A、4B、4N、4C1、4C2、4D、4F、4G、4H1和 4H2）组成的外包装组合包装；.2 样品装在塑料、玻璃、瓷器或粗陶器制成的微量滴定板或多层滴定板中，作为内包装；.3 每个内腔的最大量对于固体不超过0.01g，对于液体不超过0.01mL;.4 每个外容器的最大净量，固体为 20g，液体为 20mL，如果是混合包装，克数和毫升数之和不超过20；以及.5 当干冰或液氮可选用作质量控制措施的冷却剂时，须符合第 5.5.3 节的规定。须提供内部支撑，以将内包装固定在其原始位置。内包装和外包装须在使用的制冷剂温度下以及在失去制冷时可能产生的温度和压力下保持其完整性。 PP95 第2.0.4.3节中少量高能样品可酌情按 UN 3223 或 3224 运输，但前提是：.1 外包装仅由 4G 型瓦楞纤维板构成，其最小尺寸为 60cm（长）×40.5cm（宽） ×30cm（高），最小壁厚为1.3cm；.2 单个物质装在最大容量为 30mL 的玻璃或塑料内容器中，置于厚度至少为 130mL、密度为18±1g/L的可膨胀聚乙烯泡沫基质中； P520.3 在泡沫载体内，内包装彼此之间至少间隔 40mm，与外包装壁之间的距离至少间隔70mm。包装件最多可容纳两层此类泡沫基质，每层最多容纳28个内包装；.4 每个内包装的最大装量，固体不超过1g，液体不超过1mL；.5 每个外包装的最大净量，固体为 56g，液体为 56mL，如果是混合包装，克数和毫升数之和不超过56；以及.6 当干冰或液氮可选用作质量控制措施的冷却剂时，须符合第 5.5.3 节的规定。须提供内部支撑，以将内包装固定在其原始位置。内包装和外包装须在使用的制冷剂温度下以及在失去制冷时可能产生的温度和压力下保持其完整性。

P520 This instruction applies to organic peroxides of class 5.2 and self-reactive substances of class 4.1. The packagings listed below are authorized provided the general provisions of 4.1.1 and 4.1.3 and special provisions of 4.1.7 are met. The packing methods are designated OP1 to OP8. The packing methods appropriate for the individual currently assigned organic peroxides and self-reactive substances are listed in 2.4.2.3.2.3 and 2.5.3.2.4. The quantities specified for each packing method are the maximum quantities authorized per package. The following packagings are authorized: (1) Combination packagings with outer packagings comprising boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1 and 4H2), drums (1A1, 1A2, 1B1, 1B2, 1G, 1H1, 1H2 and 1D) and jerricans (3A1, 3A2, 3B1, 3B2, 3H1 and 3H2); (2) Single packagings consisting of drums (1A1, 1A2, 1B1, 1B2, 1G, 1H1, 1H2 and 1D) and jerricans (3A1, 3A2, 3B1, 3B2, 3H1 and 3H2); (3) Composite packagings with plastics inner receptacles (6HA1, 6HA2, 6HB1, 6HB2, 6HC, 6HD1, 6HD2, 6HG1, 6HG2, 6HH1 and 6HH2). The maximum quantities per packaging/package for packing methods OP1 to OP8 are: OP1 OP21 OP3 OP41 OP5 OP6 OP7 OP8 Maximum net mass (kg) for solids and for 0.5 0.5/10 5 5/25 25 50 50 4002 combination packagings (liquid and solid) Maximum contents in litres for liquids3 0.5 – 5 – 30 60 60 2254 If two values are given, the first applies to the maximum net mass per inner packaging and the second to the maximum net mass of the complete package. 60 kg for jerricans/200 kg for boxes and, for solids, 400 kg in combination packagings with outer packagings comprising boxes (4C1, 4C2, 4D, 4F, 4G, 4H1 and 4H2) and with inner packagings of plastics or fibre with a maximum net mass of 25 kg. Viscous liquids shall be treated as solids when they do not meet the criteria provided in the definition for liquids presented in 1.2.1. 60 L for jerricans. Additional provisions: Metal packagings, including inner packagings of combination packagings and outer packagings of combination or composite packagings, may only be used for packing methods OP7 and OP8. 4 In combination packagings, glass receptacles may only be used as inner packagings with a maximum content of 0.5 kg for solids or 0.5 L for liquids. In combination packagings, cushioning materials shall not be readily combustible. The packaging of an organic peroxide or self-reactive substance required to bear an EXPLOSIVE subsidiary hazard label (Model No. 1, see 5.2.2.2.2) shall also comply with the provisions given in 4.1.5.10 and 4.1.5.11. (continued) P520 Special packing provisions: PP21 For certain self-reactive substances of types B or C, UN Nos. 3221, 3222, 3223, 3224, 3231, 3232, 3233 and 3234, a smaller packaging than that allowed by packing methods OP5 or OP6 respectively shall be used (see 4.1.7 and 2.4.2.3.2.3). PP22 UN 3241, 2-bromo-2-nitropropane-1,3-diol, shall be packed in accordance with packing method OP6. PP94 Very small amounts of energetic samples of section 2.0.4.3 may be carried under UN 3223 or UN 3224, as appropriate, provided that:.1 only combination packaging with outer packaging comprising boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1 and 4H2) are used;.2 the samples are carried in microtiter plates or multi-titer plates made of plastics, glass, porcelain or stoneware as inner packaging;.3 the maximum amount per individual inner cavity does not exceed 0.01 g for solids or 0.01 mL for liquids;.4 the maximum net quantity per outer packaging is 20 g for solids or 20 mL for liquids, or in the case of mixed packing the sum of grams and millilitres does not exceed 20; and.5 when dry ice or liquid nitrogen is optionally used as a coolant for quality control measures, the requirements of 5.5.3 are complied with. Interior supports shall be provided to secure the inner packagings in their original position. The inner and outer packagings shall maintain their integrity at the temperature of the refrigerant used as well as the temperatures and the pressures which could result if refrigeration were lost. PP95 Small amounts of energetic samples of section 2.0.4.3 may be carried under UN 3223 or UN 3224, as appropriate, provided that:.1 the outer packaging consist only of corrugated fibreboard of type 4G having minimum dimensions of 60 cm (length) by 40.5 cm (width) by 30 cm (height) and minimum wall thickness of 1.3 cm;.2 the individual substance is contained in an inner packaging of glass or plastics of maximum capacity mL placed in an expandable polyethylene foam matrix of at least 130 mm thickness having a density of 18 1 g/L; ±.3 within the foam carrier, inner packagings are segregated from each other by a minimum distance of 40 mm and from the wall of the outer packaging by a minimum distance of 70 mm. The package may contain up to two layers of such foam matrices, each carrying up to 28 inner packagings;.4 the maximum content of each inner packaging does not exceed 1 g for solids or 1 mL for liquids;.5 the maximum net quantity per outer packaging is 56 g for solids or 56 mL for liquids, or in the case of mixed packing the sum of grams and millilitres does not exceed 56; and.6 when dry ice or liquid nitrogen is optionally used as a coolant for quality control measures, the requirements of 5.5.3 are complied with. Interior supports shall be provided to secure the inner packagings in their original position. The inner and outer packagings shall maintain their integrity at the temperature of the refrigerant used as well as the temperatures and the pressures which could result if refrigeration were lost.

出处：IMDG Code 42-24 第 216 页（4.1.4.1）

SP 274

运输单证和包装标记的正确运输名称须以技术名称作补充(见3.1.2.8.1)。 ■ 仅就UN 3077和UN 3082而言，技术名称可以是《危险货物一览表》第2栏中以大写字母显示的名称，条件是该名称不包括“N.O.S.”，且未指定特别规定274。 须使用最恰当地描述该物质或混合物的名称，例如： ■ UN 3082，环境有害物质，液体，未另列明(涂料) ■ UN 3082，环境有害物质，液体，未另列明(香水产品)。

For the purposes of documentation and package marking, the proper shipping name shall be supplemented with the technical name (see 3.1.2.8.1). For UN 3077 and UN 3082 only, the technical name may be a name shown in capital letters in column 2 of the Dangerous Goods List, provided that this name does not include “N.O.S.” and that special provision 274 is not assigned. The name which most appropriately describes the substance or mixture shall be used, e.g.: UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PAINT) UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERFUMERY PRODUCTS).

出处：IMDG Code 42-24 第 773 页

避开热源。

Protected from sources of heat.

与SGG1 - 酸类“隔离”。

Stow “separated from” SGG1 – acids.

与SGG18 - 碱类“隔离”。

Stow “separated from” SGG18 – alkalis.