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UN3292 含有金属钠或钠合金的电池或含有金属钠或钠合金的电池芯

BATTERIES, CONTAINING METALLIC SODIUM OR SODIUM ALLOY or CELLS, CONTAINING METALLIC SODIUM OR SODIUM ALLOY

IMDG Code 42-24 第4.3类 更新 2026-09-08

基本信息

UN 编号UN3292
中文名称含有金属钠或钠合金的电池或含有金属钠或钠合金的电池芯
英文名称BATTERIES, CONTAINING METALLIC SODIUM OR SODIUM ALLOY or CELLS, CONTAINING METALLIC SODIUM OR SODIUM ALLOY
危险类别第4.3类
包装类别本条目未划定包装类别
海洋污染物
有限数量0
例外数量E0
EmS 应急措施F-G,S-P(F-G, S-P)

物质性质与外观

一系列含钠的密封金属电池, 电气连接并固定在金属外壳 内。冷"电池(只含有固态钠元 素的电池)是电惰性的。电池 在工作前要加热到300°C至 350°C才能活化,从而产生电 能。激活的电池(即含有液态 钠元素的“热”电池)可能会 因端子短路而引起火灾。除非 得到主管当局的批准,并符合 主管当局规定的运输条件,否 则不得在电池或电池组中存在 液态元素钠的温度下运输电池 或电池组。

Series of hermetically sealed metal cells containing sodium, electrically connected and secured within a metal casing. “Cold” batteries (batteries containing elemental sodium only in the solid state) are electrically inert. Batteries are activated by heating to between 300 C and 350 C before operating to produce electricity. ° ° Activated batteries (i.e. “hot” batteries containing liquid elemental sodium) may cause fire through short-circuit of the terminals. Batteries or cells should not be offered for transport at a temperature such that liquid elemental sodium is present in the battery or cell unless approved, and under conditions of transport established by the competent authority.

出处:IMDG Code 42-24 第 740 页

包装要求

本条目适用的包装导则: P408 ;有限数量 0,例外数量 E0。

P408

P408 本包装导则适用于UN 3292。 只要符合第4.1.1和4.1.3节的一般规定,允许使用下列包装: (1) 电池: 桶(1A2、1B2、1N2、1H2、1D、1G); 箱(4A、4B、4N、4C1、4C2、4D、4F、4G、4H1、4H2); 罐(3A2、3B2、3H2)。 须有足够的衬垫材料,以防止电池之间以及电池与外包装内表面之间的接触,并确保在运输过程中外包装内的电池不会发生危险移动。 包装须符合包装类II的性能指标。 (2) 电池组可以不包装或装在保护性外壳中运输(例如完全封闭或木质板条箱)。电极不得承受与其他电池组一起包装的其他电池或材料的重量。 包装无需满足第4.1.1.3条的要求。 注:允许的包装净重可以超过 400kg(见第 4.1.3.3条)。 补充规定: 电池和电池组须防止短路,并以放短路的方式隔离。

P408 This instruction applies to UN 3292. The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: (1) For cells: Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G); Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2); Jerricans (3A2, 3B2, 3H2). There shall be sufficient cushioning material to prevent contact between cells and between cells and the internal surfaces of the outer packaging and to ensure that no dangerous movement of the cells within the outer packaging occurs in transport. Packagings shall conform to the packing group II performance level. (2) Batteries may be transported unpacked or in protective enclosures (e.g. fully enclosed or wooden slatted crates). The terminals shall not support the weight of other batteries or materials packed with the batteries. Packagings need not meet the requirements of 4.1.1.3. Note: The packagings authorized may exceed a net mass of 400 kg (see 4.1.3.3). Additional requirement: Cells and batteries shall be protected against short circuit and shall be isolated in such a manner as to prevent short circuits.

出处:IMDG Code 42-24 第 209 页(4.1.4.1)

中型散装容器(IBC)要求

本条目无中型散装容器(IBC)运输要求。

罐柜运输要求

本条目无罐柜运输要求(一览表罐柜导则栏为空)。

运输标签与标记

本货物包件应张贴以下标签与标记:

遇水放出易燃气体 4.3 4.3
遇水放出易燃气体 4.3

特殊规定(Special Provisions)

本条目适用特殊规定: 239401

SP 239

电池组或电池不得含有钠、硫或钠的化合物(如多硫化钠和四氯铝酸钠)以外的危险货物。除非得到主管当局批准并在其确定的条件下运输,电池组或电池不得在有液态钠元素存在的温度下运输。 电池须由密闭的金属外壳组成,这种金属外壳完全封装危险货物,其构造和密封能防止在正常运输条件下危险货物的泄漏。 电池组须由装于完全密封的金属外壳内的电池构成,其构造和封装能防止在正常运输条件下危险货物泄漏。

Batteries or cells shall not contain dangerous goods other than sodium, sulphur or sodium compounds (e.g. sodium polysulphides and sodium tetrachloroaluminate). Batteries or cells shall not be offered for transport at a temperature such that liquid elemental sodium is present in the battery or cell, unless approved and under the conditions established by the competent authority. Cells shall consist of hermetically sealed metal casings which fully enclose the dangerous goods and which are so constructed and closed as to prevent the release of the dangerous goods under normal conditions of transport. Batteries shall consist of cells secured within and fully enclosed by a metal casing so constructed and closed as to prevent the release of the dangerous goods under normal conditions of transport.

出处:IMDG Code 42-24 第 771 页

SP 401

含有机电解质的钠离子电池和电池组须按UN 3551 或 3552 运输,视情而定。含水碱性电解质的钠离子电池和电池组须按UN 2795 电池,湿式,充满碱性,电存储。

Sodium ion cells and batteries with organic electrolyte shall be transported as UN 3551 or 3552, as appropriate. Sodium ion cells and batteries with aqueous alkali electrolyte shall be transported as UN 2795 BATTERIES, WET, FILLED WITH ALKALI, electric storage.

出处:IMDG Code 42-24 第 791 页

积载与隔离

积载与操作积载类A H1(Category A H1)
隔离SG26

隔离代码(7.2.8)

SG26

补充:当在集装箱船上舱面积载时,须在横向与第 2.1 类和第 3 类保持最小两个箱位,当在滚装船上积载时,须在横向与第 2.1 类和第 3 类保持最小6米。

In addition: from goods of classes 2.1 and 3 when stowed on deck of a containership a minimum distance of two container spaces athwartship shall be maintained, when stowed on ro-ro ships a distance of 6 m athwartship shall be maintained.

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