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UN3314 塑料模料,呈柔软块团,薄片状或被挤压成丝状,放出易燃蒸气

PLASTICS MOULDING COMPOUND in dough, sheet or extruded rope form, evolving flammable vapour

IMDG Code 42-24 第9类 包装类别 III 更新 2026-09-08

基本信息

UN 编号UN3314
中文名称塑料模料,呈柔软块团,薄片状或被挤压成丝状,放出易燃蒸气
英文名称PLASTICS MOULDING COMPOUND in dough, sheet or extruded rope form, evolving flammable vapour
危险类别第9类
包装类别III
海洋污染物
有限数量5 kg
例外数量E1
EmS 应急措施F-A,S-I(F-A, S-I)

物质性质与外观

制模材料,主要由聚苯乙烯、 聚甲基丙烯酸甲酯或其他聚合 材料构成,并含有5%至8%的 挥发性烃类主要成分是戊烷。 在储存期间,少量的戊烷会释 放,至空气中;温度升高释放 量会增加。

A moulding material consisting predominantly of polystyrene, poly(methyl methacrylate) or other polymeric material and containing 5% to 8% of a volatile hydrocarbon which is predominantly pentane. During storage, a small proportion of this pentane is released to the atmosphere; this proportion increases at elevated temperatures.

出处:IMDG Code 42-24 第 741 页

包装要求

本条目适用的包装导则: P002 ;有限数量 5 kg,例外数量 E1。

P002

(固体) P002 只要符合第4.1.1和4.1.3节的一般规定,允许使用下列包装: 组合包装最大净重(见第4.1.3.3条) 玻璃 10kg 桶塑料1 30kg 钢(1A1、1A2) 125kg 400kg 400kg 金属 40kg 铝(1B1、1B2) 125kg 400kg 400kg 纸1, 2, 3 50kg 其它金属 125kg 400kg 400kg 纤维1, 2, 3 50kg (1N1,1N2) 125kg 400kg 400kg 塑料(1H1,1H2) 125kg 400kg 400kg 胶合板(1D) 125kg 400kg 400kg 纤维(1G) 箱钢(4A) 125kg 400kg 400kg 铝(4B) 125kg 400kg 400kg 其它金属(4N) 125kg 400kg 400kg 天然木(4C1) 125kg 400kg 400kg 天然木, 250kg 400kg 400kg 箱壁防筛漏(4C2) 这些内包装须防胶合板(4D) 125kg 400kg 400kg 泄漏。 再生木(4F) 125kg 400kg 400kg 在运输途中物质纤维板(4G) 75kg 400kg 400kg 可能成为液体时, 可发性塑料(4H1) 40kg 60kg 60kg 不得使用这些内包硬塑料(4H2) 125kg 400kg 400kg 装。 罐纸和纤维质内包钢(3A1、3A2) 75kg 120kg 120kg 装不得用于包装类铝(3B1、3B2) 75kg 120kg 120kg I物质。 塑料(3H1、3H2) 75kg 120kg 120kg 最大净重(见第4.1.3.3条) 单一包装包装类I 包装类II 包装类III 桶钢(1A1或1A24) 400kg 400kg 400kg 铝(1B1或1B24) 400kg 400kg 400kg 金属、除了钢或铝((1N1或1N24) 400kg 400kg 400kg 塑料(1H1或1H24) 400kg 400kg 400kg 纤维质(1G5) 400kg 400kg 400kg 胶合板(1D5) 400kg 400kg 400kg (固体) P002 4这些包装不得用于装载运输途中可能变成液体的包装类I物质(见第4.1.3.4条)。 5这些包装不得用于装载运输途中可能变成液体的物质(见第4.1.3.4条)。 只要符合第4.1.1和4.1.3节的一般规定,允许使用下列包装: 罐钢(3A1或3A24) 120kg 120kg 120kg 铝(3B1或3B24) 120kg 120kg 120kg 塑料(3H1或3H24) 120kg 120kg 120kg 箱钢(4A)5 不允许 400kg 400kg 铝(4B)5 不允许 400kg 400kg 其他金属(4N)5) 不允许 400kg 400kg 天然木(4C1)5 不允许 400kg 400kg 天然木,箱壁防筛漏(4C2)5 不允许 400kg 400kg 胶合板(4D)5 不允许 400kg 400kg 再生木(4F)5 不允许 400kg 400kg 纤维板(4G)5 不允许 400kg 400kg 硬塑料(4H2)5 不允许 400kg 400kg 袋袋(5H3,5H4,5L3,5M2)5 不允许 50kg 50kg 复合包装塑料容器,置于钢、铝、胶合板、纤维质或塑 400kg 400kg 400kg 料桶内(6HA1、6HB1、6HG15、6HD15或 6HH1) 塑料容器,置于钢或铝板条箱或箱、木箱、 75kg 75kg 75kg 胶合板箱、纤维板箱或硬塑料箱内(6HA2, 6HB2,6HC,6HD25,6HG25或6HH2) 玻璃容器,置于钢、铝、胶合板或纤维质桶 75kg 75kg 75kg 内(6PA1、6PB1、6PD15或6PG15)或置于钢、铝、木、纤维板箱或在柳条篮中 (6PA2、6PB2、6PC、6PG25、或6PD25) 或置于硬的或可发性塑料包装内(6PH2或 6PH15) 4这些包装不得用于装载运输途中可能变成液体的包装类I物质(见第4.1.3.4条)。 (固体) P002 5这些包装不得用于装载运输途中可能变成液体的物质(见第 4.1.3.4条)。 压力容器,但须符合第4.1.3.6条的一般规定。 特殊包装规定: PP7 对于UN 2000,赛璐珞可以不包装地放置在托盘上运输,用塑料薄膜包裹并用钢带等适当方式紧固作为封闭货物运输组件中的单个商品运输。每个托盘不超过1000 kg。 PP8 对于UN 2002,包装的构造须确保不会因内压升高而爆炸。不得将这些物质用于气瓶和气体容器。 PP9 对于UN 3175、3243和3244,包装须符合已经通过包装类II性能标准的防漏试验的设计类型。对于UN 3175,当液体完全被密封袋中的固体材料吸收时,无需进行防漏试验。 PP11 对于UN 1309、包装类III和UN 1362,如果5H1、5L1和5M1袋用塑料袋包装并用收缩膜或拉伸膜包裹在货盘上,则允许使用5H1、5L1和5M1袋。 PP12 对于UN 2213和3077,在封闭货物运输组件中运输时,允许使用5H1、5L1和5M1 袋。 PP13 对于UN 2870下分类的物品,只允许使用符合包装类I性能指标的组合包装。 PP14 对于UN 2211、2698和3314,包装无需符合第6.1章中的性能测试要求。 PP15 对于UN 1324和2623,包装须符合包装类III性能指标。 PP20 对于UN 2217,可以使用防筛漏、防撕裂的容器。 PP30 对于UN 2471,不允许使用纸质或纤维质内包装。 PP31 对于 UN 1362、1463、1565、1575、1626、1680、1689、1698、1868、1889、 1932、2471、2545、2546、2881、3048、3088、3170、3174、3181、3182、 3189、3190、3205、3206、3341、3342、3448、3449和3450,包装须气密封口。 PP34 对于UN 2969(整颗粒豆),允许使用5H1、5L1和5M1袋。 PP37 对于UN 2590和2212,允许使用5M1袋。任何类型的袋装货物须放在封闭的货物运输组件内运输,或置于封闭的硬质外包装中运输。 PP38 对于UN 1309,只有在封闭货物运输组件或作为组件货物时,允许使用袋。 PP84 对于UN 1057,须使用符合包装类II性能标准的硬质外包装。包装的设计、构造和布置须能防止内装物移动、设备意外着火或易燃气体或液体意外泄漏。 PP85 对于UN 1748、2208、2880、3485、3486和3487,不允许使用袋。 PP92 对于UN3531和3533,包装的设计和构造须允许释放气体或蒸汽,以防止压力积聚, 因为压力积聚可能导致包装在失去稳定性时破裂。 PP100 对于 UN1309、1323、1333、1376、1435、1449、1457、1472、1476、1483、 1509、1516、1567、1869、2210、2858、2878、2968、3089、3096 和 3125,软质、纤维板或木质容器须防筛漏和防水,或须具有防筛漏和防水的内衬。

(SOLIDS) P002 The following packagings are authorized provided the general provisions of 4.1.1 and 4.1.3 are met. Combination packagings Maximum net mass (see 4.1.3.3) Glass 10 kg Drums Plastics1 30 kg steel (1A1, 1A2) 125 kg 400 kg 400 kg Metal 40 kg aluminium (1B1, 1B2) 125 kg 400 kg 400 kg Paper 1, 2, 3 50 kg other metal (1N1, 1N2) 125 kg 400 kg 400 kg Fibre1, 2, 3 50 kg plastics (1H1, 1H2) 125 kg 400 kg 400 kg plywood (1D) 125 kg 400 kg 400 kg fibre (1G) 125 kg 400 kg 400 kg Boxes steel (4A) 125 kg 400 kg 400 kg aluminium (4B) 125 kg 400 kg 400 kg other metal (4N) 125 kg 400 kg 400 kg natural wood (4C1) 125 kg 400 kg 400 kg natural wood with 250 kg 400 kg 400 kg sift-proof walls (4C2) plywood (4D) 125 kg 400 kg 400 kg These inner packagings shall reconstituted wood (4F) 125 kg 400 kg 400 kg be sift-proof. fibreboard (4G) 75 kg 400 kg 400 kg These inner packagings expanded plastics (4H1) 40 kg 60 kg 60 kg shall not be used when the substances being transported solid plastics (4H2) 125 kg 400 kg 400 kg may become liquid during Jerricans transport (see 4.1.3.4). Paper and fibre inner steel (3A1, 3A2) 75 kg 120 kg 120 kg packagings shall not be used aluminium (3B1, 3B2) 75 kg 120 kg 120 kg for substances of packing group I. plastics (3H1, 3H2) 75 kg 120 kg 120 kg Single packagings Drums steel (1A1 or 1A24) 400 kg 400 kg 400 kg aluminium (1B1 or 1B24) 400 kg 400 kg 400 kg metal, other than steel or aluminium (1N1 or 1N24) 400 kg 400 kg 400 kg plastics (1H1 or 1H24) 400 kg 400 kg 400 kg fibre (1G5) 400 kg 400 kg 400 kg plywood (1D5) 400 kg 400 kg 400 kg These packagings shall not be used for substances of packing group I that may become liquid during transport (see 4.1.3.4). These packagings shall not be used when the substances being transported may become liquid during transport (see 4.1.3.4). (SOLIDS) (continued) P002 The following packagings are authorized provided the general provisions of 4.1.1 and 4.1.3 are met. Maximum net mass (see 4.1.3.3) Single packagings (continued) Packing group I Packing group II Packing group III Jerricans steel (3A1 or 3A24) 120 kg 120 kg 120 kg aluminium (3B1 or 3B24) 120 kg 120 kg 120 kg plastics (3H1 or 3H24) 120 kg 120 kg 120 kg Boxes steel (4A)5 Not allowed 400 kg 400 kg aluminium (4B)5 Not allowed 400 kg 400 kg other metal (4N)5 Not allowed 400 kg 400 kg natural wood (4C1)5 Not allowed 400 kg 400 kg natural wood with sift-proof walls (4C2)5 Not allowed 400 kg 400 kg plywood (4D)5 Not allowed 400 kg 400 kg reconstituted wood (4F)5 Not allowed 400 kg 400 kg fibreboard (4G)5 Not allowed 400 kg 400 kg solid plastics (4H2)5 Not allowed 400 kg 400 kg Bags bags (5H3, 5H4, 5L3, 5M2)5 Not allowed 50 kg 50 kg Composite packagings Plastics receptacle in steel, aluminium, plywood, fibre or 400 kg 400 kg 400 kg plastics drum (6HA1, 6HB1, 6HG15, 6HD15, or 6HH1) Plastics receptacle in steel or aluminium crate or box, 75 kg 75 kg 75 kg wooden box, plywood box, fibreboard box or solid plastics box (6HA2, 6HB2, 6HC, 6HD25, 6HG25 or 6HH2) Glass receptacle in steel, aluminium, plywood or fibre 75 kg 75 kg 75 kg drum (6PA1, 6PB1, 6PD15 or 6PG15) or in steel, aluminium, wood, or fibreboard box or in wickerwork hamper (6PA2, 6PB2, 6PC, 6PG25 or 6PD25) or in expanded or solid plastics packaging (6PH2 or 6PH15) 4 These packagings shall not be used for substances of packing group I that may become liquid during transport (see 4.1.3.4). These packagings shall not be used when the substances being transported may become liquid during transport (see 4.1.3.4). Pressure receptacles, provided that the general provisions of 4.1.3.6 are met. Special packing provisions: PP7 For UN 2000, celluloid may be transported unpacked on pallets, wrapped in plastic film and secured by appropriate means, such as steel bands, as a single commodity in closed cargo transport units. Each pallet shall not exceed 1,000 kg. PP8 For UN 2002, packagings shall be so constructed that explosion is not possible by reason of increased internal pressure. Gas cylinders and gas receptacles shall not be used for these substances. PP9 For UN Nos. 3175, 3243 and 3244, packagings shall conform to a design type that has passed a leakproofness test at the packing group II performance level. For UN 3175 the leakproofness test is not required when the liquids are fully absorbed in solid material contained in sealed bags. PP11 For UN 1309, packing group III, and UN 1362, 5H1, 5L1 and 5M1 bags are allowed if they are overpacked in plastic bags and are wrapped in shrink or stretch wrap on pallets. PP12 For UN Nos. 2213 and 3077, 5H1, 5L1 and 5M1 bags are allowed when transported in closed cargo transport units. PP13 For articles classified under UN 2870, only combination packagings meeting the packing group I performance level are authorized. PP14 For UN Nos. 2211, 2698 and 3314, packagings are not required to meet the performance tests in chapter 6.1. PP15 For UN Nos. 1324 and 2623, packagings shall meet the packing group III performance level. PP20 For UN 2217, any sift-proof, tearproof receptacle may be used. PP30 For UN 2471, paper or fibre inner packagings are not permitted. PP31 For UN Nos. 1362, 1463, 1565, 1575, 1626, 1680, 1689, 1698, 1868, 1889, 1932, 2471, 2545, 2546, 2881, 3048, 3088, 3170, 3174, 3181, 3182, 3189, 3190, 3205, 3206, 3341, 3342, 3448, 3449 and 3450, packagings shall be hermetically sealed. PP34 For UN 2969 (as whole beans), 5H1, 5L1 and 5M1 bags are permitted. PP37 For UN Nos. 2590 and 2212, 5M1 bags are permitted. All bags of any type shall be transported in closed cargo transport units or be placed in closed rigid overpacks. PP38 For UN 1309, bags are permitted only in closed cargo transport units or as unit loads. PP84 For UN 1057, rigid outer packagings meeting the packing group II performance level shall be used. The packagings shall be designed and constructed and arranged to prevent movement, inadvertent ignition of the devices or inadvertent release of flammable gas or liquid. PP85 For UN Nos. 1748, 2208, 2880, 3485, 3486 and 3487, bags are not allowed. PP92 For UN Nos. 3531 and 3533, packagings shall be designed and constructed to permit the release of gas or vapour to prevent a build-up of pressure that could rupture the packagings in the event of loss of stabilization. PP100 For UN numbers 1309, 1323, 1333, 1376, 1435, 1449, 1457, 1472, 1476, 1483, 1509, 1516, 1567, 1869, 2210, 2858, 2878, 2968, 3089, 3096 and 3125, flexible, fibreboard or wooden packagings shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-resistant liner.

出处:IMDG Code 42-24 第 171 页(4.1.4.1)

包装特殊规定

PP14

对于UN 2211、2698和3314,包装无需符合第6.1章中的性能测试要求。

For UN Nos. 2211, 2698 and 3314, packagings are not required to meet the performance tests in chapter 6.1.

中型散装容器(IBC)要求

IBC08

IBC08 只要符合第4.1.1、4.1.2和4.1.3节的一般规定,允许使用下列IBCs: 金属(11A、11B、11N、21A、21B、21N、31A、31B 和 31N); 硬质塑料(11H1、11H2、21H1、21H2、31H1 和 31H2); 复合包装(11HZ1、11HZ2、21HZ1、21HZ2 和 31HZ1); 纤维板(11G); 木质包装(11C、11D和11F); 软质包装(13H1、13H2、13H3、13H4、13H5、13L1、13L2、13L3、13L4、13M1 IBC08 或13M2)。 补充规定: 如果在运输期间固体变成液体,请参见第4.1.3.4条。 特殊包装规定: B3 软质IBCs须防筛漏和防水,或装配防筛漏和防水内衬。 B4 软质、纤维板或木制IBCs须防筛漏和防水,或配备防筛漏和防水内衬。 B6 对于 UN 1327、1363、1364、1365、1386、1408、1841、2211、2217、2793 和 3314的IBCs,无需满足第6.5章的IBCs试验要求。 B21 除了金属或硬质塑料 IBCs,对于盛装固体物质的 IBCs 须装在封闭货物运输组件或货运集装箱/货运车辆内运输,货物运输组件或货运集装箱/货运车辆须具有至少与IBCs高度相同的硬质侧壁或围栏。

IBC08 The following IBCs are authorized, provided the general provisions of 4.1.1, 4.1.2 and 4.1.3 are met: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2 and 31HZ1); Fibreboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2). Additional provisions: Where the solid may become liquid during transport see 4.1.3.4. Special packing provisions: B3 Flexible IBCs shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-resistant liner. B4 Flexible, fibreboard or wooden IBCs shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-resistant liner. B6 For UN Nos. 1327, 1363, 1364, 1365, 1386, 1408, 1841, 2211, 2217, 2793 and 3314, IBCs are not required to meet the IBC testing provisions of chapter 6.5. B21 For solid substances in IBCs other than metal or rigid plastics IBCs, the IBCs shall be carried in closed cargo transport units or in freight containers/vehicles, which shall have rigid sides or fences at least to the height of the IBC.

罐柜运输要求

本条目无罐柜运输要求(一览表罐柜导则栏为空)。

运输标签与标记

本货物包件应张贴以下标签与标记:

杂项危险物质 9 9
杂项危险物质 9

本 UN 可按有限数量运输(一览表额度 5kg);若本票按限量运输,须加贴 LQ 标记并符合第 3.4 章要求

本 UN 可按例外数量运输(代码 E1);若本票按例外数量运输,须加贴 EQ 标记并符合第 3.5 章要求

特殊规定(Special Provisions)

本条目适用特殊规定: 207965

SP 207

制模化合物可以由聚苯乙烯、聚(甲基丙烯酸甲酯)或其他聚合材料制成。

Plastics moulding compounds may be made from polystyrene, poly(methyl methacrylate) or other polymeric material.

出处:IMDG Code 42-24 第 769 页

SP 965

.1 当使用货物运输组件式时,该组件须提供适当的空气交换(即:使用通风集装箱、开顶式集装箱或一个门打开的集装箱),以防止爆炸气体的形成。也可选择在控温下符合第7.3.7.6条规定的冷冻集装箱运输这些条目。当使用通风装置的货物运输组件时,这些装置须是清洁和可操作的。当使用机械通风时,须是防爆的,以防止释放的易燃气体被点燃。.2.1的规定不适用下列情况:.1 该物质的包装或IBCs是气密包件,并分别符合第6.1或6.5章的规定,达到液体危险货物包装类II的要求;和.2 该包装或IBCs标记的液压试验压,按照第4.1.1.10.1条要求,超过 55℃充灌货物时包装或IBCs内的总表压的1.5倍。.3 该物质在封闭货物运输组件运输时,须符合第7.3.6.1条的规定。.4 货物运输组件须标有警告标记,包括“注意 - 可能含有易燃气体”字样, 字体高度不低于25 mm。该标记须贴在装货处的每一入口点的位置, 在打开或进入货物运输组件之前,易于被人看到,并须保留在货物运输组件上直到满足下列规定:.1 该货物运输组件已彻底通风,清除任何危险浓度的气体或蒸气;.2 货物运输组件的附近没有任何火源;和.3 货物已卸载。

.1 When transported in cargo transport units, the cargo transport units shall provide an adequate exchange of air in the unit (e.g. by using a ventilated container, open-top container or container in one door off operation) to prevent the build-up of an explosive atmosphere. Alternatively, these entries shall be transported under temperature control in refrigerated cargo transport units that comply with the provisions of 7.3.7.6. When cargo transport units with venting devices are used, these devices shall be kept clear and operable. When mechanical devices are used for ventilation, they shall be explosion-proof to prevent ignition of flammable vapours from the substances..2 The provisions of.1 do not apply if:.1 the substance is packed in hermetically sealed packagings or IBCs, which conform to packing group II performance level for liquid dangerous goods according to the provisions of 6.1 or 6.5, respectively; and.2 the marked hydraulic test pressure exceeds 1.5 times the total gauge pressure in the packagings or IBCs determined at 55C for the respective filling goods according to ° 4.1.1.10.1..3 Where the substance is loaded in closed cargo transport units, the provisions of 7.3.6.1 shall be met..4 C argo transport units shall be marked with a warning mark including the words “CAUTION – MAY CONTAIN FLAMMABLE VAPOUR” with lettering not less than 25 mm high. This mark shall be affixed at each access point in a location where it will be easily seen by persons prior to opening or entering the cargo transport unit and shall remain on the cargo transport unit until the following provisions are met:.1 the cargo transport unit has been completely ventilated to remove any hazardous concentration of vapour or gas;.2 the immediate vicinity of the cargo transport unit is clear of any source of ignition; and.3 t he goods have been unloaded.

出处:IMDG Code 42-24 第 795 页

积载与隔离

积载与操作积载类E SW1 SW6(Category E SW1 SW6)
隔离SG5 SG14

积载操作代码(SW)

SW1

避开热源。

Protected from sources of heat.

SW6

在舱内积载时,机械通风须满足《安全公约》第II-2/19(II-2/54)条关于闪点低于23℃(c.c.)的易燃液体的规定。

When stowed under deck, mechanical ventilation shall be in accordance with SOLAS regulation II-2/19 (II-2/54) for flammable liquids with flashpoint below 23C c.c. °

隔离代码(7.2.8)

SG5

按第3类隔离。

Segregation as for class 3.

SG14

与除1.4S外的第1类“隔离”。

Stow “separated from” class 1 except for division 1.4S.

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按 UN3314 自动带出类别、包装组、隔离要求与危包证清单,省掉翻书对表的时间。

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