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UN3392 有机金属物质,液体的,引火的

ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC

IMDG Code 42-24 第4.2类 包装类别 I 更新 2026-09-08

基本信息

UN 编号UN3392
中文名称有机金属物质,液体的,引火的
英文名称ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC
危险类别第4.2类
包装类别I
海洋污染物
有限数量0
例外数量E0
EmS 应急措施F-G,S-M(F-G, S-M)

物质性质与外观

极易燃液体。在空气中易于自 发着火。与空气接触,放出刺 激性的、小毒性烟雾。

Highly flammable liquid. Liable to ignite spontaneously in air. In contact with air, evolve irritating and slightly toxic fumes.

出处:IMDG Code 42-24 第 749 页

包装要求

本条目适用的包装导则: P400 ;有限数量 0,例外数量 E0。

P400

P400 只要符合第4.1.1和4.1.3节的一般规定,允许使用下列包装: (1) 符合第 4.1.3.6条的一般规定的压力容器。压力容器须由钢制成,并须在不低于 1MPa (10bar, 表压)的压力下进行初次试验,并在以后每隔10年进行定期检验。在运输过程中,液面须处于表压不低于20Kpa(0.2bar)的惰性气体层下。 (2) 箱 (4A、4B、4N、4C1、4C2、4D、4F 或 4G)、桶(1A1、1A2、1B1、1B2、 1N1、1N2、1D或1G)或罐 (3A1、3A2、3B1或3B2)内装有密封的金属罐,每个金属罐的容量不超过 1L,内容器为玻璃或金属,并配有密封垫。内容器须有螺纹封盖或用任何能够防止运输过程中撞击或振动导致封盖脱落或松动的物理固定装置。内容器的所有侧面均须垫以干燥、吸水、不易燃材料,其数量足以吸收全部内装物。内容器的最大充灌度不得超过其容量的90%。外包装的最大净重为125 kg。 (3) 钢桶、铝桶或其他金属桶(1A1、1A2、1B1、1B2、1N1 或 1N2)、罐(3A1、3A2、 3B1或 3B2)或箱(4A、4B或 4N),每个最大净重为 150kg,每个金属内罐密封,容量不超过 4L,封盖配有垫圈。内容器须有螺纹封盖或用任何能够防止运输过程中因撞击或振动而脱落或松动的物理固定装置。内容器的所有侧面均须垫以干燥、吸水、不易燃材料,衬垫量须足以吸收全部内装物。除垫衬材料外,每层内容器还须有分隔板隔开。内容器的最大充灌度不得超过其容量的90%。 特殊包装规定: PP86 对于UN 3392和3394,须使用氮气或其他方法消除蒸气空间中的空气。

P400 The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met: (1) Pressure receptacles, provided that the general provisions of 4.1.3.6 are met. They shall be made of steel and shall be subjected to an initial test and periodic tests every 10 years at a pressure of not less than 1 MPa (10 bar, gauge pressure). During carriage, the liquid shall be under a layer of inert gas with a gauge pressure of not less than kPa (0.2 bar). (2) Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F or 4G), drums (1A1, 1A2, 1B1, 1B2, 1N1, 1N2, 1D or 1G) or jerricans (3A1, 3A2, 3B1 or 3B2) enclosing hermetically sealed metal cans with inner packagings of glass or metal, with a capacity of not more than 1 L each, having closures with gaskets. Inner packagings shall have threaded closures or closures physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transport. Inner packagings shall be cushioned on all sides with dry, absorbent, non-combustible material in a quantity sufficient to absorb the entire contents. Inner packagings shall not be filled to more than 90% of their capacity. Outer packagings shall have a maximum net mass of 125 kg. (3) Steel, aluminium or metal drums (1A1, 1A2, 1B1, 1B2, 1N1 or 1N2), jerricans (3A1, 3A2, 3B1 or 3B2) or boxes (4A, 4B or 4N) with a maximum net mass of 150 kg each with hermetically sealed inner metal cans of not more than L capacity each, with closures fitted with gaskets. Inner packagings shall have threaded closures or closures physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transport. Inner packagings shall be cushioned on all sides with dry, absorbent, non-combustible material in a quantity sufficient to absorb the entire contents. Each layer of inner packagings shall be separated by a dividing partition in addition to cushioning material. Inner packagings shall not be filled to more than 90% of their capacity. Special packing provision: PP86 For UN Nos. 3392 and 3394, air shall be eliminated from the vapour space by nitrogen or other means.

出处:IMDG Code 42-24 第 204 页(4.1.4.1)

包装特殊规定

PP86

对于UN 3392和3394,须使用氮气或其他方法消除蒸气空间中的空气。

For UN Nos. 3392 and 3394, air shall be eliminated from the vapour space by nitrogen or other means.

中型散装容器(IBC)要求

本条目无中型散装容器(IBC)运输要求。

罐柜运输要求

T21

T1-T22 本可移动罐柜导则适用于第1类和第3至9类液体和固体物质,须满足第4.2.1节的一般规定和第6.7.2节的要求。带 FRP 外壳的可移动罐柜导则适用于第 1、3、5.1、6.1、6.2、8 和 9 类或小类物质。此外,第 6.10 章的规定适用于带 FRP 外壳的可移动罐柜。 最小罐壳厚度底部开口最低试验 (单位: mm-标准安全减压规定a 规定b 可移动罐柜导则压力钢) (见第6.7.2.8 (见第6.7.2.6 (bar) (见第6.7.2.4 条) 条) 条) 10 10mm 正常不允许

S T1 – T22 These portable tank instructions apply to liquid and solid substances of class 1 and classes 3 to 9. The general provisions of section 4.2.1 and the requirements of section 6.7.2 shall be met. The instructions for portable tanks with FRP shells apply to substances of classes or divisions 1, 3, 5.1, 6.1, 6.2, 8 and 9. Additionally, the provisions of chapter 6.10 apply to the portable tanks with FRP shells. Minimum shell thickness Pressure relief Bottom opening (in mm – reference provisionsa provisionsb instruction pressure (bar) steel) (see 6.7.2.8) (see 6.7.2.6) (see 6.7.2.4) 10 10 mm Normal Not allowed

罐柜特殊规定

TP2

不得超过第4.2.1.9.3条中规定的充灌度。

The degree of filling prescribed in 4.2.1.9.3 shall not be exceeded.

TP7

须使用氮气或其他方式将蒸气空间中的空气排除。

Air shall be eliminated from the vapour space by nitrogen or other means.

TP36

可移动罐柜可使用蒸气空间的可熔元件。  TP37 删除  TP38 删除  TP39 删除

Fusible elements in the vapour space may be used on portable tanks.

运输标签与标记

本货物包件应张贴以下标签与标记:

易自燃物质 4.2 4.2
易自燃物质 4.2

特殊规定(Special Provisions)

本条目适用特殊规定: 274

SP 274

运输单证和包装标记的正确运输名称须以技术名称作补充(见3.1.2.8.1)。 ■ 仅就UN 3077和UN 3082而言,技术名称可以是《危险货物一览表》第2栏中以大写字母显示的名称,条件是该名称不包括“N.O.S.”,且未指定特别规定274。 须使用最恰当地描述该物质或混合物的名称,例如: ■ UN 3082,环境有害物质,液体,未另列明(涂料) ■ UN 3082,环境有害物质,液体,未另列明(香水产品)。

For the purposes of documentation and package marking, the proper shipping name shall be supplemented with the technical name (see 3.1.2.8.1). For UN 3077 and UN 3082 only, the technical name may be a name shown in capital letters in column 2 of the Dangerous Goods List, provided that this name does not include “N.O.S.” and that special provision 274 is not assigned. The name which most appropriately describes the substance or mixture shall be used, e.g.: UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PAINT) UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERFUMERY PRODUCTS).

出处:IMDG Code 42-24 第 773 页

积载与隔离

积载与操作积载类D H1(Category D H1)
隔离SG26 SG63 SG72

隔离代码(7.2.8)

SG26

补充:当在集装箱船上舱面积载时,须在横向与第 2.1 类和第 3 类保持最小两个箱位,当在滚装船上积载时,须在横向与第 2.1 类和第 3 类保持最小6米。

In addition: from goods of classes 2.1 and 3 when stowed on deck of a containership a minimum distance of two container spaces athwartship shall be maintained, when stowed on ro-ro ships a distance of 6 m athwartship shall be maintained.

SG63

与第1类货物用一个介于中间的整个舱室或货舱作纵向隔离。

Stow “separated longitudinally by an intervening complete compartment or hold from” class 1.

SG72

见表7.2.6.3。

See tables in 7.2.6.3.

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